EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.111 | 9beta-pimara-7,15-diene + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Oryza sativa |
3beta-hydroxy-9beta-pimara-7,15-dien-19,6beta-olide + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.111 | more |
CYP99A3 catalyzes consecutive oxidations of the C19 methyl group of the momilactone precursor syn-pimara-7,15-diene to form, sequentially, syn-pimaradien-19-ol, syn-pimaradien-19-al, and syn-pimaradien-19-oate |
Oryza sativa |
? |
- |
? |
1.14.14.111 | syn-pimara-7,15-diene + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Oryza sativa |
syn-pimaradien-19-ol + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.111 | syn-pimaradien-19-al + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Oryza sativa |
syn-pimaradien-19-oate + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.111 | syn-pimaradien-19-ol + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Oryza sativa |
syn-pimaradien-19-al + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.111 | syn-stemod-13(17)-ene + [reduced NADPH-hemoprotein reductase] + O2 |
about 4fold lower catalytic efficiency than with syn-pimaradiene, oxidation occurs at C19 |
Oryza sativa |
syn-stemoden-19-ol + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.111 | syn-stemoden-19-al + [reduced NADPH-hemoprotein reductase] + O2 |
about 4fold lower catalytic efficiency than with syn-pimaradiene, oxidation occurs at C19 |
Oryza sativa |
syn-stemoden-19-oate + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.111 | syn-stemoden-19-ol + [reduced NADPH-hemoprotein reductase] + O2 |
about 4fold lower catalytic efficiency than with syn-pimaradiene, oxidation occurs at C19 |
Oryza sativa |
syn-stemoden-19-al + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |