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Information on EC 1.14.14.111 - 9beta-pimara-7,15-diene oxidase

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IUBMB Comments
A cytochrome P-450 (heme-thiolate) protein. The enzyme from rice (Oryza sativa) is involved in the biosynthesis of the phytoalexin momilactone. It also acts similarly on 9beta-stemod-13(17)-ene.
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The expected taxonomic range for this enzyme is: Oryza sativa
Synonyms
CYP99A3, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
9beta-pimara-7,15-dien-19-al + O2 + [reduced NADPH-hemoprotein reductase] = 9beta-pimara-7,15-dien-19-oate + [oxidized NADPH-hemoprotein reductase] + H2O
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(1c)
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9beta-pimara-7,15-dien-19-ol + O2 + [reduced NADPH-hemoprotein reductase] = 9beta-pimara-7,15-dien-19-al + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
(1b)
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9beta-pimara-7,15-diene + 3 O2 + 3 [reduced NADPH-hemoprotein reductase] = 9beta-pimara-7,15-dien-19-oate + 3 [oxidized NADPH-hemoprotein reductase] + 4 H2O
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overall reaction
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9beta-pimara-7,15-diene + O2 + [reduced NADPH-hemoprotein reductase] = 9beta-pimara-7,15-dien-19-ol + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
(1a)
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