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EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
4.2.1.127
(R,S)-linalool
the enzyme is not stereospecific
Thauera linaloolentis 47Lol
beta-myrcene + H2O
-
r
4.2.1.127
2-methylbut-3-en-2-ol
-
Castellaniella defragrans
2-methylbuta-1,3-diene + H2O
-
r
4.2.1.127
3-ethyloct-1-en-3-ol
-
Castellaniella defragrans
(3E)-3-ethylidene-7-methylocta-1,6-diene + H2O
-
r
4.2.1.127
3-methoxy-3,7-dimethylocta-1,6-diene
-
Castellaniella defragrans
beta-myrcene
-
r
4.2.1.127
3-methyl-5-phenylpent-1-en-3-ol
-
Castellaniella defragrans
(3-methylidenepent-4-en-1-yl)benzene + H2O
-
r
4.2.1.127
3-methylhept-1-en-3-ol
-
Castellaniella defragrans
3-methylidenehept-1-ene + H2O
-
r
4.2.1.127
3-methylhex-1-en-3-ol
-
Castellaniella defragrans
3-methylidenehex-1-ene + H2O
-
r
4.2.1.127
beta-myrcene + H2O
-
Castellaniella defragrans
(3S)-linalool
-
?
4.2.1.127
beta-myrcene + H2O
stereospecific reaction, introduction of the hydroxy group on the si-face of beta-myrcene
Castellaniella defragrans
(3S)-linalool
(3S)-linalool is formed with an enantiomeric excess of at least 95.4%, (3R)-inalool is not detected
?
4.2.1.127
beta-myrcene + H2O
-
Castellaniella defragrans 65Phen
(3S)-linalool
-
?
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