EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
5.5.1.17 | (S)-beta-bisabolene |
- |
Zea mays |
(S)-beta-macrocarpene |
- |
? |
5.5.1.17 | (S)-beta-bisabolene |
- |
Zea mays |
(S)-beta-macrocarpene |
i.e. (1'S)-4',5,5-trimethyl-1,1'-bi(cyclohexane)-1,3'-diene. Product is identified by GC-MS |
? |
5.5.1.17 | (S)-beta-bisabolene |
the enzyme may be involved in plant defense |
Zea mays |
(S)-beta-macrocarpene |
- |
? |
5.5.1.17 | (S)-beta-bisabolene |
the enzyme may be involved in plant defense |
Zea mays |
(S)-beta-macrocarpene |
i.e. (1'S)-4',5,5-trimethyl-1,1'-bi(cyclohexane)-1,3'-diene. Product is identified by GC-MS |
? |
5.5.1.17 | (S)-beta-bisabolene |
the synthesis of (S)-macrocarpene from (2E,6E)-farnesyl diphosphate in two steps. The first step is the cyclization to (S)-beta-. The second step is the isomerization to (S)-beta-macrocarpene ((S)-beta-macrocarpene synthase) |
Zea mays |
(S)-beta-macrocarpene |
i.e. (1'S)-4',5,5-trimethyl-1,1'-bi(cyclohexane)-1,3'-diene. Product is identified by GC-MS |
? |
5.5.1.17 | (S)-beta-bisabolene |
(S)-beta-macrocarpene formation by TPS11 requires a protonation of the (S)-beta-bisabolene intermediate |
Zea mays |
(S)-beta-macrocarpene |
- |
? |
5.5.1.17 | geranyl diphosphate |
- |
Zea mays |
(S)-beta-bisabolene + (S)-beta-macrocarpene |
in the presence of geranylgeranyl diphosphate, TPS11 also catalyzes the formation of beta-myrcene and linalool, along with minor amounts of limonene, alpha-thujene, sabinene, and alpha-terpinolene |
? |
5.5.1.17 | more |
no enzymatic activity is observed in the presence of geranylgeranyl diphosphate |
Zea mays |
? |
- |
? |