EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
4.2.3.116 | (3R)-linalyl diphosphate |
(3R)-enantiomer is preferred over (3S)-enantiomer |
Salvia officinalis |
(+)-camphene + diphosphate |
products are (+)-camphene and (+)alpha-pinene |
? |
4.2.3.116 | (3S)-linalyl diphosphate |
(3R)-enantiomer is preferred over (3S)-enantiomer |
Salvia officinalis |
(-)-camphene + diphosphate |
products are (-)-camphene and (-)alpha-pinene |
? |
4.2.3.116 | geranyl diphosphate |
- |
Salvia officinalis |
(+)-camphene + diphosphate |
31% (+)-alpha-pinene, 29% (+)-camphene |
? |
4.2.3.116 | geranyl diphosphate |
- |
Salvia officinalis |
(+)-camphene + diphosphate |
products are (+)-alpha-pinene and (+)-camphene |
? |
4.2.3.116 | geranyl diphosphate |
- |
Salvia officinalis |
(+)-camphene + diphosphate |
products are (+)-camphene and (+)alpha-pinene |
? |
4.2.3.116 | geranyl diphosphate |
- |
Salvia officinalis |
(+)-camphene + diphosphate |
products are (+)-camphene, (+)-alpha-pinene and (+)-limonene |
? |
4.2.3.116 | geranyl diphosphate |
- |
Salvia officinalis |
(+)-camphene + diphosphate |
products are 25% (+)-alpha-pinene, 25% (+)-camphene, 43% (+)-limonene, and 7% myrcene. Reaction in organic solvent gives the same olefin distribution as in aqueous buffer |
? |
4.2.3.116 | geranyl diphosphate |
- |
Lavandula angustifolia |
(+)-camphene + diphosphate |
products are 39% (+)-limonene, 22% terpinolene, 16% (+)-camphene, 14% (+)-alpha-pinene, 8% beta-myrcene, 1% alpha-phellandrene. Product pattern changes markedly to 46% limonene, 9% terpinolene, 23% alpha-pinene, 5% beta-myrcene and 4% alpha-phellandrene, when Mn2+ is supplied instead of Mg2+ |
? |
4.2.3.116 | geranyl diphosphate |
stereochemistry is not specified in the publication |
Artemisia annua |
camphene + diphosphate |
- |
? |
4.2.3.116 | more |
enzyme removes the C4-proR-hydrogen of the substrate, the C3 proton trans to the dimethyl bridge of the pinyl nucleus, with a stereoselectivity exceeding 94% in the formation of (+)-alpha-pinene |
Salvia officinalis |
? |
- |
? |