EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
  4.2.3.10 | 2,3-cyclopropylgeranyl diphosphate |
at 53% of the rate of conversion of geranyl diphosphate, formation of ether-soluble products |
Anethum foeniculum |
? |
- |
? |
| 4.2.3.10 | 6,7-dihydrogeranyl diphosphate |
at 35% of the rate of conversion of geranyl diphosphate, formation of ether-soluble products |
Anethum foeniculum |
? |
- |
? |
| 4.2.3.10 | dimethylallyl diphosphate |
at the same rate as the cyclization of geranyl diphosphate |
Anethum foeniculum |
dimethylallyl alcohol + diphosphate |
- |
? |
| 4.2.3.10 | farnesyl diphosphate |
at 25% of the rate of conversion of geranyl diphosphate, formation of ether-soluble products |
Anethum foeniculum |
? |
- |
? |
| 4.2.3.10 | geranyl diphosphate |
- |
Anethum foeniculum |
(-)-endo-fenchol + diphosphate |
- |
? |
| 4.2.3.10 | geranyl diphosphate |
mechanism of the isomerization-cyclization reaction |
Anethum foeniculum |
(-)-endo-fenchol + diphosphate |
- |
? |
| 4.2.3.10 | geranyl diphosphate |
stereochemistry, syn-isomerization of substrate to (3R)-linalyl diphosphate and cyclization of the latter via the anti-endo-conformer |
Anethum foeniculum |
(-)-endo-fenchol + diphosphate |
- |
? |
| 4.2.3.10 | geranyl diphosphate |
(3R)-linalyl diphosphate is an intermediate in the reaction |
Anethum foeniculum |
(-)-endo-fenchol + diphosphate |
- |
? |
| 4.2.3.10 | geranyl diphosphate |
biosynthesis of monoterpenes |
Anethum foeniculum |
(-)-endo-fenchol + diphosphate |
- |
? |
| 4.2.3.10 | geranyl diphosphate + H2O |
- |
Lavandula pedunculata |
alpha-fenchol + diphosphate |
products are 72% alpha-fenchol, 8.7% alpha-pinene, 14.1% limonene, 2.3% alpha-terpinolene |
? |
