EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
   1.11.1.18 | 2,4-dibromophenol + bromide + H2O2 |
- |
Leptoxyphium fumago |
2,4,6-tribromophenol + 2 H2O |
- |
? |
| 1.11.1.18 | 4-bromophenol + bromide + H2O2 |
- |
Leptoxyphium fumago |
2,4-dibromophenol + 2 H2O |
- |
? |
| 1.11.1.18 | beta-estradiol + bromide + H2O2 |
- |
Leptoxyphium fumago |
? + 2 H2O |
- |
? |
| 1.11.1.18 | beta-estradiol + chloride + H2O2 |
- |
Leptoxyphium fumago |
? + 2 H2O |
- |
? |
| 1.11.1.18 | Br- + H2O2 + (3E,6R,7R)-laurediol |
- |
Laurencia nipponica |
deacetyllaurencin + H2O |
- |
? |
| 1.11.1.18 | Br- + H2O2 + (3R)-3-bromo-2,6-dimethylhept-5-en-2-ol |
- |
Ascophyllum nodosum |
3,5-dibromo-2,6-dimethylheptane-2,6-diol + H2O |
70% yield, at pH 6.0 |
? |
| 1.11.1.18 | Br- + H2O2 + 1-methoxynaphthalene |
- |
Corallina pilulifera |
1-methoxy-4-bromonaphthalene + H2O |
- |
? |
| 1.11.1.18 | Br- + H2O2 + 1-phenylpent-4-en-1-ol |
- |
Ascophyllum nodosum |
4-bromo-1-phenylpentane-1,5-diol + 5-bromo-1-phenylpentane-1,4-diol + 2-(bromomethyl)-5-phenyltetrahydrofuran + H2O |
30% yield of 4-bromo-1-phenylpentane-1,5-diol, 28% yield of 5-bromo-1-phenylpentane-1,4-diol, and 25% yield of 2-(bromomethyl)-5-phenyltetrahydrofuran, at pH 6.0 |
? |
| 1.11.1.18 | Br- + H2O2 + 2,4,6-tribromophenol |
- |
Corallina officinalis |
1,3,6,8-tetrabromodibenzo-p-dioxin |
formation of ppb-level yields of 1,3,6,8-tetrabromodibenzo-p-dioxin through direct condensation. Additionally, 1,3,7,9-tetrabromodibenzo-p-dioxin, 1,2,4,7-tetrabromodibenzo-p-dioxin, and/or 1,2,4,8-tetrabromodibenzo-p-dioxin and 1,3,7-tribromodibenzo-p-dioxin and 1,3,8-tribromodibenzo-p-dioxin are frequently formed but at lower yields. Reaction probably proceeds via bromine shifts or Smiles rearrangements, whereas the tribromodibenzo-p-dioxins may result from subsequent debromination processes |
? |
| 1.11.1.18 | Br- + H2O2 + 2-hydroxybenzyl alcohol |
- |
Corallina pilulifera |
2,4,6-tribromobenzyl alcohol + H2O |
- |
? |
