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Results 1 - 8 of 8
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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 1.1.1.3174-nitroacetophenone + NADPH + H+ - Rauvolfia serpentina 4-nitrobenzylalcohol + NADP+ - ?
Display the reaction diagram Show all sequences 1.1.1.3174-nitrobenzaldehyde + NADPH + H+ - Rauvolfia serpentina 4-nitrobenzoate + NADP+ - ?
Display the reaction diagram Show all sequences 1.1.1.317more probable dual functionality of perakine reductase, which may not only include alkaloid biosynthesis but may also include function in phenylpropanoid metabolism, generating cinnamic alcohols Rauvolfia serpentina ? - ?
Display the reaction diagram Show all sequences 1.1.1.317more the enzyme also catalyses the reduction of coniferyl aldehyde, sinapyl aldehyde, 4-coumaryl aldehyde, 3-(3,4,5-trimethoxyphenyl)propenal Rauvolfia serpentina ? - ?
Display the reaction diagram Show all sequences 1.1.1.317more enantioselective 1,2-reduction of alpha,beta-unsaturated ketones and aryl ketones by perakine reductase. Perakine reductase catalyzes asymmetric reduction of enones and aromatic ketones, leading to alpha-allylic alcohols and alpha-aromatic alcohols. It is NADPH-dependent. Among the evaluated substances, 4'-nitroacetophenone is found to be the best ketone substrate, with yield and enantiomeric excess values exceeding 99%. Exclusive enantioselectivity of enzyme perakine reductase (PR) Rauvolfia serpentina ? - -
Display the reaction diagram Show all sequences 1.1.1.317perakine + NADPH + H+ - Rauvolfia serpentina raucaffrinoline + NADP+ - ?
Display the reaction diagram Show all sequences 1.1.1.317perakine + NADPH + H+ the biosynthesis of raucaffrinoline from perakine is a side route of the ajmaline biosynthesis pathway (monoterpenoid indole alkaloid) Rauvolfia serpentina raucaffrinoline + NADP+ - ?
Display the reaction diagram Show all sequences 1.1.1.317perakine + NADPH + H+ NADPH can not be replaced by NADH. In presence of the oxidized cofactor NADP+ the reverse reaction of the reductase is low, with less than 0.5% relative activity of the forward reaction Rauvolfia serpentina raucaffrinoline + NADP+ - ?
Results 1 - 8 of 8
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