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EC Number BRENDA No. Title Journal Volume Pages Year Organism PubMed ID
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23764973 Steric enforcement of cis-epoxide formation in the radical C-O-coupling reaction by which (S)-2-hydroxypropylphosphonate epoxidase (HppE) produces fosfomycin J. Am. Chem. Soc. 141 20397-20406 2019 Streptomyces wedmorensis 31769979
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23706480 Structure and reactivity of hydroxypropylphosphonic acid epoxidase in fosfomycin biosynthesis by a cation- and flavin-dependent mechanism Proc. Natl. Acad. Sci. USA 102 14221-14226 2005 Streptomyces wedmorensis 16186494
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23704155 Protein purification and function assignment of the epoxidase catalyzing the formation of fosfomycin J. Am. Chem. Soc. 123 4619-4620 2001 Streptomyces wedmorensis 11457256
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23704157 Oxygenase activity in the self-hydroxylation of (S)-2-hydroxypropylphosphonic acid epoxidase involved in fosfomycin biosynthesis J. Am. Chem. Soc. 126 10306-10312 2004 Streptomyces wedmorensis 15315444
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23727675 Evidence for radical-mediated catalysis by HppE: a study using cyclopropyl and methylenecyclopropyl substrate analogues J. Am. Chem. Soc. 134 16171-16174 2012 Streptomyces wedmorensis 23006053
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23727696 Reaction of HppE with substrate analogues: evidence for carbon-phosphorus bond cleavage by a carbocation rearrangement J. Am. Chem. Soc. 135 8153-8156 2013 Streptomyces wedmorensis 23672451
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23729898 Mechanistic consequences of chiral radical clock probes: analysis of the mononuclear non-heme iron enzyme HppE with 2-hydroxy-3-methylenecyclopropyl radical clock substrates J. Am. Chem. Soc. 136 2944-2947 2014 Streptomyces wedmorensis 24512048
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23702547 On the conversion of structural analogues of (S)-2-hydroxypropylphosphonic acid to epoxides by the final enzyme of fosfomycin biosynthesis in S. fradiae Bioorg. Med. Chem. Lett. 18 3056-3059 2008 Streptomyces fradiae 18155909
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23727328 On the catalytic mechanism of (S)-2-hydroxypropylphosphonic acid epoxidase (HppE): a hybrid DFT study Chemistry 19 771-781 2013 Streptomyces wedmorensis 23150463
Display the word mapDisplay the reaction diagram Show all sequences 1.11.1.23705742 Cloning and nucleotide sequence of fosfomycin biosynthetic genes of Streptomyces wedmorensis Mol. Gen. Genet. 249 274-280 1995 Streptomyces wedmorensis 7500951
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