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EC Number	Natural Substrates	Commentary (Nat. Sub.)
2.4.1.269	GDP-alpha-D-glucose + D-glycerate	the enzyme catalyzes the formation of the stress protectant 2-O-alpha-D-mannosyl glycerate
2.4.1.269	GDP-mannose + D-glycerate	Rhodothermus marinus possesses two enzymatic systems for the synthesis of mannosylglycerate. The first one is a single-step pathway in which mannosylglycerate synthase catalyses the synthesis of 2-O-(alpha-D-mannopyranosyl)-D-glycerate in one-step from GDP-mannose and D-glycerate. The second system is a two-step pathway in which mannosyl-3-phosphoglycerate synthase (EC 2.4.1.217) catalyses the conversion of GDP-mannose and 3-phospho-D-glycerate into 2-O-(alpha-D-mannopyranosyl)-3-phospho-D-glycerate, which is then converted to 2-O-(alpha-D-mannopyranosyl)-D-glycerate by mannosyl-3-phosphoglycerate phosphatase (EC 3.1.3.70)

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Release 2023.1 (January 2023)