EC Number |
Natural Substrates |
---|
1.14.14.45 | (E)-4-hydroxyphenylacetaldoxime + O2 + [reduced NADPH-hemoprotein reductase] |
- |
1.14.14.45 | (E)-indol-3-ylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 |
- |
1.14.14.45 | (E)-p-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 |
- |
1.14.14.45 | (E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 |
- |
1.14.14.45 | 1-aci-nitro-2-(4-hydroxyphenyl)-ethane + 2-mercaptoethanol |
- |
1.14.14.45 | an (E)-omega-(methylthio)alkanal oxime + O2 + glutathione + [reduced NADPH-hemoprotein reductase] |
- |
1.14.14.45 | indole-3-acetaldoxime + [reduced NADPH-hemoprotein reductase] + O2 |
- |
1.14.14.45 | more |
CYP83B1 catalyzes the conversion of the (E)-p-hydroxyphenylacetaldoxime into an S-alkyl-thiohydroximate with retention of the configuration of the E-oxime intermediate in the final glucosinolate core structure. CYP83B1 from Arabidopsis thaliana cannot convert the (E)-p-hydroxyphenylacetaldoxime to the (Z)-isomer, which blocks the route towards cyanogenic glucoside synthesis |