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Literature summary extracted from

  • Rodriguez, C.; De Gonzalo, G.; Fraaije, M.W.; Gotor, V.
    Enzymatic kinetic resolution of racemic ketones catalyzed by Baeyer-Villiger monooxygenases (2007), Tetrahedron Asymmetry, 18, 1338-1344.
No PubMed abstract available

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.14.13.84 additional information
-
 additional information kinetic resolution of the racemic carbonyl compounds, overview Pseudomonas fluorescens

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.14.13.84 4-hydroxyacetophenone + NADPH + H+ + O2 Pseudomonas fluorescens
-
 4-hydroxyphenyl acetate + NADP+ + H2O
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.14.13.84 Pseudomonas fluorescens
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.13.84 (R)-2-phenylpentan-3-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
1.14.13.84 (R)-3-phenylbutan-2-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
1.14.13.84 (R)-3-phenylpentan-2-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
1.14.13.84 (R)-4-phenylhexan-2-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
1.14.13.84 2-phenylpentan-3-one + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
1.14.13.84 2-phenylpropionaldehyde + NADPH + H+ + O2
-
 Pseudomonas fluorescens ?
-
 ?
1.14.13.84 4-hydroxyacetophenone + NADPH + H+ + O2
-
 Pseudomonas fluorescens 4-hydroxyphenyl acetate + NADP+ + H2O
-
 ?
1.14.13.84 4-hydroxyacetophenone + NADPH + H+ + O2 enantiospecific reaction, overview Pseudomonas fluorescens 4-hydroxyphenyl acetate + NADP+ + H2O
-
 ?
1.14.13.84 additional information a Bayer-Villinger monooxygenase, substrate specificity with several racemic cyclic and linear ketones, as well as 2-phenylpropionaldehyde, high enantioselectivites can be obtained in the kinetic resolution processes depending on the substrate structure and the reaction conditions, overview Pseudomonas fluorescens ?
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.14.13.84 HAPMO
-
 Pseudomonas fluorescens

pH Optimum

EC Number pH Optimum Minimum pH Optimum Maximum Comment Organism
1.14.13.84 8 9 assay at Pseudomonas fluorescens

pH Range

EC Number pH Minimum pH Maximum Comment Organism
1.14.13.84 6 10 effects of pH on enantioselectivity, overview Pseudomonas fluorescens

Cofactor

EC Number Cofactor Comment Organism Structure
1.14.13.84 NADPH
-
 Pseudomonas fluorescens