EC Number | Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|---|
5.5.1.22 | geranyl diphosphate | Salvia officinalis | - |
(-)-bornyl diphosphate | i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate | ? | |
5.5.1.22 | geranyl diphosphate | Tanacetum vulgare | - |
(-)-bornyl diphosphate | i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate | ? |
EC Number | Organism | UniProt | Comment | Textmining |
---|---|---|---|---|
5.5.1.8 | Salvia officinalis | - |
- |
- |
5.5.1.8 | Tanacetum vulgare | - |
- |
- |
5.5.1.22 | Salvia officinalis | - |
- |
- |
5.5.1.22 | Tanacetum vulgare | - |
- |
- |
EC Number | Reaction | Comment | Organism | Reaction ID |
---|---|---|---|---|
5.5.1.8 | geranyl diphosphate = (+)-bornyl diphosphate | mechanism | Salvia officinalis | |
5.5.1.8 | geranyl diphosphate = (+)-bornyl diphosphate | mechanism | Tanacetum vulgare | |
5.5.1.8 | geranyl diphosphate = (+)-bornyl diphosphate | geranyl diphosphate is first stereospecifically isomerized to linalyl diphosphate which, following rotation about C-2-B-3 to the cisoid conformer, cyclizes from the anti-endo configuration. Neryl diphosphate cyclizes either directly or via the linalyl intermediate without the attendant rotation | Salvia officinalis | |
5.5.1.8 | geranyl diphosphate = (+)-bornyl diphosphate | geranyl diphosphate is first stereospecifically isomerized to linalyl diphosphate which, following rotation about C-2-B-3 to the cisoid conformer, cyclizes from the anti-endo configuration. Neryl diphosphate cyclizes either directly or via the linalyl intermediate without the attendant rotation | Tanacetum vulgare |
EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|---|
5.5.1.8 | Geranyl diphosphate | - |
Salvia officinalis | (+)-Bornyl-diphosphate | - |
? | |
5.5.1.8 | Geranyl diphosphate | - |
Tanacetum vulgare | (-)-Bornyl-diphosphate | - |
? | |
5.5.1.22 | geranyl diphosphate | - |
Salvia officinalis | (-)-bornyl diphosphate | i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate | ? | |
5.5.1.22 | geranyl diphosphate | - |
Tanacetum vulgare | (-)-bornyl diphosphate | i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate | ? | |
5.5.1.22 | geranyl diphosphate | reaction mechanism whereby geranyl diphosphate is first stereospecifically isomerized to linalyl diophosphate which, following rotation about C-2-C-3 to the cisoid conformer, cyclizes from the anti-endo configuration | Salvia officinalis | (-)-bornyl diphosphate | i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate | ? | |
5.5.1.22 | geranyl diphosphate | reaction mechanism whereby geranyl diphosphate is first stereospecifically isomerized to linalyl pyrophosphawte which, following rotation about C-2-C-3 to the cisoid conformer, cyclizes from the anti-endo configuration | Tanacetum vulgare | (-)-bornyl diphosphate | i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate | ? | |
5.5.1.22 | neryl diphosphate | neryl diphosphate cyclizes either directly or via the linalyl intermediate without the attendant rotation | Salvia officinalis | (-)-bornyl diphosphate | - |
? | |
5.5.1.22 | neryl diphosphate | neryl pyrophosphate cyclizes either directly or via the linalyl intermediate without the attendant rotation | Tanacetum vulgare | (-)-bornyl diphosphate | - |
? |