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IUBMB Comments The enzyme, characterized from the bacterium Clostridium sp. MSTE9, is involved in a D -sulfoquinovose degradation pathway.
Synonyms sqwGH ,
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6-deoxy-6-sulfo-erythrulose transketolase
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sqwGH
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4-deoxy-4-sulfo-D-erythrulose + D-glyceraldehyde-3-phosphate = D-xylulose-5-phosphate + sulfoacetaldehyde
(2)
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6-deoxy-6-sulfo-D-fructose + D-glyceraldehyde-3-phosphate = D-xylulose-5-phosphate + 4-deoxy-4-sulfo-D-erythrose
(1)
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MetaCyc
sulfoquinovose degradation V
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6-deoxy-6-sulfo-D-fructose:D-glyceraldehyde-3-phosphate glycolaldehydetransferase
The enzyme, characterized from the bacterium Clostridium sp. MSTE9, is involved in a D-sulfoquinovose degradation pathway.
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4-deoxy-4-sulfo-D-erythrulose + D-glyceraldehyde-3-phosphate
D-xylulose-5-phosphate + sulfoacetaldehyde
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Substrates: -
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6-deoxy-6-sulfo-D-fructose + D-glyceraldehyde-3-phosphate
D-xylulose-5-phosphate + 4-deoxy-4-sulfo-D-erythrose
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Substrates: -
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4-deoxy-4-sulfo-D-erythrulose + D-glyceraldehyde-3-phosphate
D-xylulose-5-phosphate + sulfoacetaldehyde
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Substrates: -
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6-deoxy-6-sulfo-D-fructose + D-glyceraldehyde-3-phosphate
D-xylulose-5-phosphate + 4-deoxy-4-sulfo-D-erythrose
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Substrates: -
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brenda
Highest Expressing Human Cell Lines
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evolution
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in diverse anaerobic bacteria including Firmicutes, Tenericutes, Spirochaetes, and Thermotogae bacteria, a sulfoquinone degradation pathway contains a mutarotase SqvB, an isomerase SqvD, a transketolase SqwGH, a homologue of ribose-5-phosphate isomerase SqwI, a metal-dependent alcohol dehydrogenase SqwF, and a member of the sulfite/sulfonate exporter family SqwE. This suggests a pathway involving isomerization of sulfoquinone to 6-deoxy-6-sulfofructose by SqvD, cleavage of 6-deoxy-6-sulfofructose by SqwGH, reduction of an aldehyde-containing sulfonate by SqwF, followed by export of the sulfonate end-product by SqwE
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SQWG_CLOS9
Clostridium sp. (strain MSTE9)
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30165
Swiss-Prot
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SQWH_CLOS9
Clostridium sp. (strain MSTE9)
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34605
Swiss-Prot
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Liu, J.; Wei, Y.; Ma, K.; An, J.; Liu, X.; Liu, Y.; Ang, E.; Zhao, H.; Zhang, Y.
Mechanistically diverse pathways for sulfoquinovose degradation in bacteria
ACS Catal.
11
14740-14750
2021
Clostridium sp. MSTE9
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brenda
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