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EC Number Cofactor Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.108S-adenosyl-L-methionine dependent on 725093
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.108[4Fe-4S]-center - 758825, 759402, 759511, 759725
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.108[4Fe-4S]-center cleavage of a S-adenosyl-L-methionine analogue, in which the 3-amino-3-carboxypropyl group is replaced with a 3-carboxyallyl group, yields a paramagnetic (S = 1/2) species, which is assigned to a complex formed between the reaction product, alpha-sulfinyl-3-butenoic acid, and the [4Fe-4S] cluster. Data support a pi-complex between the C=C double bond of alpha-sulfinyl-3-butenoic acid and the unique iron of the [4Fe-4S] cluster, i.e. a radical S-adenosyl-L-methionine-related [4Fe-4S]+ cluster forming an organometallic complex with an alkene 738461
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