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Results 1 - 10 of 24 > >>
EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-10,12-octadecadienoate - Gaeumannomyces graminis (7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-10,12-octadecadienoate - Gaeumannomyces graminis var.graminis (7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate - Gaeumannomyces graminis (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate bifunctional enzyme with linoleic acid (8R)-dioxygenase and hydroperoxide isomerase activities. The enzyme abstracts the 8-pro-S hydrogen from linoleic acid, which is followed by antarafacial insertion of molecular oxygen at C-8 to generate 8R-hydroperoxylinoleate. The latter is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxy-9,12-octadecadienoate by elimination of the 7-pro-S hydrogen and intramolecular suprafacial insertion of an oxygen atom from the hydroperoxide group Gaeumannomyces graminis (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate bifunctional enzyme with linoleic acid 8R-dioxygenase and hydroperoxide isomerase activities. The enzyme abstracts the 8-pro-S hydrogen from linoleic acid, which is followed by antarafacial insertion of molecular oxygen at C-8 to generate 8R-hydroperoxylinoleate. The latter is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxy-9,12-octadecadienoate by elimination of the 7-pro-S hydrogen and intramolecular suprafacial insertion of an oxygen atom from the hydroperoxide group Gaeumannomyces graminis (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate expression in Pichia pastoris changes the position and stereospecificity of a hydroperoxide isomerase (the recombinant enzyme forms 5,8(R)-dihydroxylinoleic acid (60% 5S) and 8(R),13-dihydroxyoctadeca-(9E,11E)-dienoic acid) possibly due to N- or O-linked mannosides in the vicinity of the heme group, whereas the (8R)-dioxygenase activity is identical with native 7,8-linoleate diol synthase Gaeumannomyces graminis (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate - Gaeumannomyces graminis var. graminis (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate bifunctional enzyme with linoleic acid (8R)-dioxygenase and hydroperoxide isomerase activities. The enzyme abstracts the 8-pro-S hydrogen from linoleic acid, which is followed by antarafacial insertion of molecular oxygen at C-8 to generate 8R-hydroperoxylinoleate. The latter is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxy-9,12-octadecadienoate by elimination of the 7-pro-S hydrogen and intramolecular suprafacial insertion of an oxygen atom from the hydroperoxide group Gaeumannomyces graminis var. graminis (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate - Gaeumannomyces graminis var. avenae (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Display the reaction diagram Show all sequences 5.4.4.6(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate expression in Pichia pastoris changes the position and stereospecificity of a hydroperoxide isomerase (the recombinant enzyme forms 5,8(R)-dihydroxylinoleic acid (60% 5S) and 8(R),13-dihydroxyoctadeca-(9E,11E)-dienoic acid) possibly due to N- or O-linked mannosides in the vicinity of the heme group, whereas the (8R)-dioxygenase activity is identical with native 7,8-linoleate diol synthase Gaeumannomyces graminis var. avenae (7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate - ?
Results 1 - 10 of 24 > >>