EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
4.4.1.34 | (3R)-3,4-epoxy-3-methylbut-1-ene + glutathione |
- |
Rhodococcus sp. |
2-(glutathion-S-yl)-2-methylbut-3-en-1-ol |
- |
? |
4.4.1.34 | (3R)-3,4-epoxy-3-methylbut-1-ene + glutathione |
i.e. isoprene monoxide. Nucleophilic attack of GSH occurs on the tertiary carbon atom of the epoxide ring |
Rhodococcus sp. |
2-(glutathion-S-yl)-2-methylbut-3-en-1-ol |
i.e. 1-hydroxy-2-glutathionyl-2-methyl-3-butene |
? |
4.4.1.34 | 1,2-epoxybutane + glutathione |
26% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
2-(glutathion-S-yl)-butan-1-ol |
- |
? |
4.4.1.34 | 1,2-epoxyhexane + glutathione |
25% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
2-(glutathion-S-yl)-hexan-1-ol |
- |
? |
4.4.1.34 | cis-1,2-dichloroepoxyethane + glutathione |
- |
Rhodococcus sp. |
1,2-dichloro-2-(glutathion-S-yl)-ethan-1-ol |
- |
? |
4.4.1.34 | cis-1,2-dichloroepoxyethane + glutathione |
4% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
1,2-dichloro-2-(glutathion-S-yl)-ethan-1-ol |
- |
? |
4.4.1.34 | cis-2,3-epoxybutane + glutathione |
13% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
3-(glutathion-S-yl)-butan-2-ol |
- |
? |
4.4.1.34 | epibromohydrin + glutathione |
25% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
3-bromo-2-(glutathion-S-yl)-propan-1-ol |
- |
? |
4.4.1.34 | epichlorohydrin + glutathione |
31% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
3-chloro-2-(glutathion-S-yl)-propan-1-ol |
- |
? |
4.4.1.34 | epifluorohydrin + glutathione |
28% of the activity with (3R)-3,4-epoxy-3-methylbut-1-ene |
Rhodococcus sp. |
3-fluoro-2-(glutathion-S-yl)-propan-1-ol |
- |
? |