EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
   2.5.1.34 | 2-pentenyl diphosphate + L-tryptophan |
very low activity, the alkylation shifts from C-4 to C-5 for FgaPT2, which can be explained by the longer chain length and thus deeper extension of 2-pentenyl diphosphate into the reaction chamber in comparison to that of dimethylallyl diphosphate, so that C-1' of the alkyl residue is closer to C-5 than C-4 in FgaPT2 |
Aspergillus fumigatus |
diphosphate + 5-(2-trans-pentenyl)-L-tryptophan |
- |
? |
| 2.5.1.34 | 2-pentenyl diphosphate + L-tryptophan |
C-5 prenylation |
Aspergillus fumigatus |
diphosphate + 5-(pent-2-enyl)-L-tryptophan |
- |
? |
| 2.5.1.34 | 4-dimethylallyl-indole-3-lactic acid |
10.5% of the activity with L-Trp |
Aspergillus fumigatus |
? |
- |
? |
| 2.5.1.34 | 4-dimethylallyl-indole-3-pyruvic acid |
29.4% of the activity with L-Trp |
Aspergillus fumigatus |
? |
- |
? |
| 2.5.1.34 | benzyl diphosphate + L-tryptophan |
C-5 prenylation |
Aspergillus fumigatus |
diphosphate + 5-benzyl-L-tryptophan |
- |
? |
| 2.5.1.34 | dimethylallyl diphosphate + 1-methyl-L-tryptophan |
- |
Aspergillus fumigatus |
diphosphate + 1-methyl-4-(3-methylbut-2-enyl)-L-tryptophan |
0.4% of the yield with L-tryptophan |
? |
| 2.5.1.34 | dimethylallyl diphosphate + 1-methyl-L-tryptophan |
- |
Malbranchea aurantiaca |
diphosphate + 1-methyl-4-(3-methylbut-2-enyl)-L-tryptophan |
3.2% of the yield with L-tryptophan |
? |
| 2.5.1.34 | dimethylallyl diphosphate + 1-naphthol |
- |
Aspergillus fumigatus |
diphosphate + ? |
- |
? |
| 2.5.1.34 | dimethylallyl diphosphate + 11-methyl-DL-tryptophan |
- |
Aspergillus fumigatus |
diphosphate + 11-methyl-DL-4-(gamma,gamma-dimethylallyl)tryptophan |
1.6% of the yield with L-tryptophan |
? |
| 2.5.1.34 | dimethylallyl diphosphate + 11-methyl-DL-tryptophan |
- |
Aspergillus fumigatus |
? |
- |
? |
