EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.52 | (+)-limonene + NADPH + O2 |
hydroxylation at the same rate as (-)-limonene |
Perilla frutescens |
perillyl alcohol + NADP+ + H2O |
- |
? |
1.14.14.52 | (-)-(S)-limonene + NADPH + O2 |
- |
Mycobacterium sp. |
(-)-perillyl alcohol + NADP+ + H2O |
- |
? |
1.14.14.52 | (-)-(S)-limonene + NADPH + O2 |
- |
Mycobacterium sp. HXN-1500 |
(-)-perillyl alcohol + NADP+ + H2O |
- |
? |
1.14.14.52 | (-)-limonene + NADPH + O2 |
highly specific |
Perilla frutescens |
perillyl alcohol + NADP+ + H2O |
- |
? |
1.14.14.52 | (-)-limonene + NADPH + O2 |
one of the key reactions of oxygenated monoterpenes, perillyl aldehyde biosynthesis |
Perilla frutescens |
perillyl alcohol + NADP+ + H2O |
- |
? |
1.14.14.52 | (S)-limonene + NADPH + H+ + O2 |
- |
Perilla frutescens |
(-)-perillyl alcohol + NADP+ + H2O |
- |
? |
1.14.14.52 | more |
no substrates: isolimonenes, terpinolene, alpha- or beta-phellandrene, alpha- or beta-terpinene, bicyclic monoterpenes: pinene, sabinene, alpha-thujene, p-cymene, cis- or trans-p-menthane, p-menth-1-ene, i.e. 8,9-dihydrolimonene |
Perilla frutescens |
? |
- |
? |
1.14.14.52 | more |
the kinetically competent recombinant protein produces a mixture of C3-, C6- and C7-hydroxylated limonene derivatives, i.e. (-)-perillyl alcohol, (-)-trans-isopiperitenol, and (-)-trans-carveol, with a distribution of 33%, 14% and 53%, respectively, thus it performs the reaction of EC 1.14.13.47 and 1.14.13.48, overview |
Perilla frutescens |
? |
- |
? |