EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.37 | (E)-4-Hydroxyphenylacetaldehyde oxime |
- |
Sorghum bicolor |
(Z)-4-Hydroxyphenylacetaldehyde oxime |
- |
? |
1.14.14.37 | (E)-4-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Sorghum bicolor |
(S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
- |
? |
1.14.14.37 | (E)-4-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Sorghum bicolor |
(S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
overall reaction |
? |
1.14.14.37 | (E)-4-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Sorghum bicolor |
(S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
overall reaction. NADPH is a much better cofactor for NADPH-hemoprotein reductase than NADH although NADH does support the entire catalytic cycle |
? |
1.14.14.37 | (E)-4-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 |
involved in dhurrin synthesis |
Sorghum bicolor |
(S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
- |
? |
1.14.14.37 | (E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 |
oxime dervied from phenylalanine, 35% of the activity with (E)-4-hydroxyphenylacetaldehyde oxime |
Sorghum bicolor |
(S)-mandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
- |
? |
1.14.14.37 | (Z)-3-methylbutanaloxime + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Hordeum vulgare |
2-hydroxy-3-methylbutyronitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
- |
? |
1.14.14.37 | (Z)-4-hydroxyphenylacetaldehyde oxime |
- |
Sorghum bicolor |
4-hydroxyphenylacetonitrile + H2O |
- |
? |
1.14.14.37 | 2-hydroxy(p-hydroxyphenyl)acetaldoxime |
poor substrate |
Sorghum bicolor |
4-hydroxymandelonitrile + H2O |
- |
? |
1.14.14.37 | 4-hydroxyphenylacetonitrile + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Sorghum bicolor |
(S)-4-hydroxymandelonitrile + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |