EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
- |
Bacillus subtilis |
(3Z)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
- |
Bacillus subtilis 168 |
(3Z)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
- |
Bacillus subtilis |
(3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
- |
Bacillus subtilis 168 |
(3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate also undergoes a nonenzymatic isomerization |
Bacillus subtilis |
(3Z)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
3-[(4S)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate also undergoes a nonenzymatic isomerization |
Bacillus subtilis 168 |
(3Z)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
nonenzymatic isomerization gives (3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate and (3Z)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate in the ratio 50:1. Isomerization by BacB gives a 3:1 mixture of the E- and Z-isomers |
Bacillus subtilis |
(3Z)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
nonenzymatic isomerization gives (3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate and (3Z)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate in the ratio 50:1. Isomerization by BacB gives a 3:1 mixture of the E- and Z-isomers |
Bacillus subtilis 168 |
(3Z)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
nonenzymatic isomerization gives (3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate and (3Z)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate in the ration 50:1. Isomerization by BacB gives a 3:1 mixture of the E- and Z-isomers |
Bacillus subtilis |
(3E)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |
5.3.3.19 | 3-[(4R)-4-hydroxycyclohexa-1,5-dien-1-yl]-2-oxopropanoate |
nonenzymatic isomerization gives (3E)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate and (3Z)-3-[(4S)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate in the ration 50:1. Isomerization by BacB gives a 3:1 mixture of the E- and Z-isomers |
Bacillus subtilis 168 |
(3E)-3-[(4R)-4-hydroxycyclohex-2-en-1-ylidene]-2-oxopropanoate |
- |
? |