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Results 1 - 2 of 2
EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
(2E,6E)-farnesyl diphosphate
MrTPS2 shows a broader sesquiterpene product spectrum with the angular triquinane, alpha-isocomene, being the main compound. The enzyme produces detectable amounts of three other triquinanes, beta-isocomene, silphinene and modeph-2-ene. Like MrTPS1 it also produces (E)-beta-caryophyllene and alpha-humulene, but in low amounts
alpha-isocomene + diphosphate
-
?
(2E,6E)-farnesyl diphosphate
reaction mechanism most likely involves repeated cycles of protonation/deprotonation of a neutral (-)-(E)-beta-caryophyllene intermediate. The deprotonation of the final isocomyl carbocation can occur either at C1 or C13, resulting in the main product alpha-isocomene and the minor product beta-isocomene
(-)-alpha-isocomene + diphosphate
-
?
Results 1 - 2 of 2