EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
2.5.1.109 | dimethylallyl diphosphate + cyclo-L-Trp-Xaa |
- |
Aspergillus oryzae |
diphosphate + 7-(3-methylbut-2-enyl)-cyclo-L-Trp-Xaa |
- |
? |
2.5.1.109 | more |
the enzyme uses cyclic dipeptides containing L-Trp and attaches the prenyl moiety to C-7 of the indole ring. The enzyme showsma relatively narrow substrate specificity |
Aspergillus oryzae |
? |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + brevianamide F |
the enzyme is involved in the alkaloid biosynthetic pathway |
Aspergillus sp. |
diphosphate + deoxybrevianamide E |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + brevianamide F |
the enzyme is specific for brevianamide F i.e. (3S,8aS)-3-(1H-indol-3-ylmethyl)hexahydropyrrolo[1,2-a]pyrazine-1,4-dione |
Aspergillus sp. |
diphosphate + deoxybrevianamide E |
deoxybrevianamide E i.e. (3S,8aS)-3-[[2-(2-methylbut-3-en-2-yl)-1H-indol-3-yl]methyl]-octahydropyrrolo[1,2-a]piperazine-1,4-dione |
? |
2.5.1.109 | dimethylallyl diphosphate + brevianamide F |
- |
Aspergillus sp. MF297-2 |
diphosphate + deoxybrevianamide E |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + brevianamide F |
i.e. cyclo-L-Trp-L-Pro, conversion yield of 66% |
Aspergillus sp. MF297-2 |
diphosphate + deoxybrevianamide E |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + cyclo-D-Trp-D-Ala |
conversion yield of 1% |
Aspergillus sp. MF297-2 |
? |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + cyclo-D-Trp-D-Ala |
conversion yield of less than 3% |
Aspergillus sp. MF297-2 |
? |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + cyclo-D-Trp-D-Pro |
conversion yield of 6% |
Aspergillus sp. MF297-2 |
? |
- |
? |
2.5.1.109 | dimethylallyl diphosphate + cyclo-D-Trp-L-Ala |
conversion yield of 17% |
Aspergillus sp. MF297-2 |
? |
- |
? |