EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.1.9.1 | (R)-3-bromo-2-methyl-1-propanol + ferricyanide |
- |
Comamonas testosteroni |
(R)-3-bromo-2-methyl-propanal + ferrocyanide |
- |
r |
1.1.9.1 | (R)-solketal aldehyde + ferrocyanide |
- |
Comamonas testosteroni |
(R)-solketal + ferricyanide |
- |
r |
1.1.9.1 | (R)-solketal aldehyde + ferrocyanide |
(R)-enantiomer is prefered, enantiomeric ratio is 2.8 for initial rate measurement |
Comamonas testosteroni |
(R)-solketal + ferricyanide |
- |
r |
1.1.9.1 | (R)-solketal + 2 ferricyanide |
(R)-enantiomer is prefered, enantiomeric ratio is 30 |
Comamonas testosteroni |
(R)-solketal aldehyde + 2 ferrocyanide + 2 H+ |
- |
r |
1.1.9.1 | (S)-solketal + 2 ferricyanide |
the second step in (S)-solketal conversion is much faster than the first one and that opposite enantiomeric preferences exist for the alcohol and the aldehyde substrates. (R)-enantiomer is prefered, enantiomeric ratio is 30 for initial rate measurement, 117 for progress curve analysis |
Comamonas testosteroni |
(S)-solketal aldehyde + 2 ferrocyanide + 2 H+ |
- |
r |
1.1.9.1 | butanal + ferrocyanide |
ADH IIB, 32% of the activity with 1-butanol. ADH IIG, 13% of the activity with 1,2-propanediol |
Pseudomonas putida |
1-butanol + ferricyanide |
- |
? |
1.1.9.1 | butanal + reduced N,N,N',N'-tetramethyl-p-phenylenediamine |
- |
Comamonas testosteroni |
1-butanol + N,N,N',N'-tetramethyl-p-phenylenediamine |
- |
r |
1.1.9.1 | octanal + reduced N,N,N',N'-tetramethyl-p-phenylenediamine |
- |
Comamonas testosteroni |
1-octanol + N,N,N',N'-tetramethyl-p-phenylenediamine |
- |
r |
1.1.9.1 | propanal + ferrocyanide |
ADH IIB, 125% of the activity with 1-butanol. ADH IIG, 58% of the activity with 1,2-propanediol |
Pseudomonas putida |
1-propanol + ferricyanide |
- |
? |
1.1.9.1 | glycerol + ferrocyanide |
ADH IIB, 0% of the activity with 1-butanol. ADH IIG, 63% of the activity with 1,2-propanediol |
Pseudomonas putida |
2,3-dihydroxypropanal + ferricyanide |
- |
? |