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EC Number General Information Commentary Reference
Display the reaction diagram Show all sequences 4.2.3.203metabolism in wild-type, there is a great thermodynamic preference for hydropyrene and hydropyrenol formation. The synthesis of the isoelisabethatriene byproducts is under kinetic control. to IEs A and B as well as hydropyrene and hydropyrenol. In the reactions generating isoelisabethatrienes there is an exchange of two pi-bonds for sigma-bonds, resulting in a total exergonicity of -34.4 and -35.9 kcal/mol, respectively. The reactions to hydropyrene and hydropyrol replace four pi-bonds for sigma-bonds and share a common final carbocation, the exergonicity is -62.8 kcal/mol. These values reflect the energetics of exchanging pi-bonds for sigma-bonds 768950
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