EC Number   |
Reaction |
Reference |
|---|
    4.4.1.13 | 2-aminoprop-2-enoate = 2-iminopropanoate |
spontaneous |
- |
| 4.4.1.13 | 2-iminopropanoate + H2O = pyruvate + NH3 |
spontaneous |
- |
| 4.4.1.13 | an L-cysteine-S-conjugate + H2O = a thiol + NH3 + pyruvate |
activation energy for reaction with L-djenkolate is 53.1 kJ/mol |
34678 |
| 4.4.1.13 | an L-cysteine-S-conjugate + H2O = a thiol + NH3 + pyruvate |
overall reaction |
- |
| 4.4.1.13 | an L-cysteine-S-conjugate + H2O = a thiol + NH3 + pyruvate |
R may represent aromatic compounds such as 4-bromobenzene and 2,4-dinitorbenzene |
- |
| 4.4.1.13 | an L-cysteine-S-conjugate + H2O = a thiol + NH3 + pyruvate |
stereochemistry |
34729 |
| 4.4.1.13 | an L-cysteine-S-conjugate + H2O = a thiol + NH3 + pyruvate |
with an amino acid containing a good leaving group in the beta position, beta-elemination is greatly favoured over transamination |
640043 |
| 4.4.1.13 | an L-cysteine-S-conjugate = a thiol + 2-aminoprop-2-enoate |
(1a) |
- |
| 4.4.1.13 | L-cystathionine + H2O = L-homocysteine + pyruvate + NH3 |
mechanism |
34714 |
| 4.4.1.13 | L-cystathionine + H2O = L-homocysteine + pyruvate + NH3 |
overall reaction |
- |
