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EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.37(2E,6E)-farnesyl diphosphate = (+)-epi-isozizaene + diphosphate - -
Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.37(2E,6E)-farnesyl diphosphate = (+)-epi-isozizaene + diphosphate ionization and isomerization of farnesyl diphosphate will give (3R)-nerolidyl diphosphate. Rotation about the newly generated C-2/C-3 bond generates the corresponding cisoid nerolidyl diphosphate conformer which can undergo ionization and cyclization to form a bisabolyl cation. Following 1,2-hydride shift and spirocyclization, the resultant acorenyl cation can undergo further cyclization, ring contraction, methyl migration, and deprotonation to yield (+)-epi-isozizaene -, 687275
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