EC Number   |
Reaction |
Reference |
|---|
   4.2.3.135 | (2E,6E)-farnesyl diphosphate = DELTA6-protoilludene + diphosphate |
- |
- |
| 4.2.3.135 | (2E,6E)-farnesyl diphosphate = DELTA6-protoilludene + diphosphate |
1,11-ring closure of (2E,6E)-farnsyl diphosphate yields a highly reactive trans-humulyl carbocation. A 1,2-hydride shift followed by further ring closures results in the protoilludyl cation, which undergoes a final deprotonation to give DELTA6-protoilludene |
729595 |
| 4.2.3.135 | (2E,6E)-farnesyl diphosphate = DELTA6-protoilludene + diphosphate |
in the presence of Ca2+, DELTA6-protoilludene synthases catalyze diverse cyclization reactions. DELTA6-Protoilludene and (E)-beta-caryophyllene result from a 1,11 cyclization of (2E,6E)-farnesyl diphosphate following metal ion mediated ionization. The intermediate trans-humulyl cation may undergo a hydride shift followed by two cyclizations and a deprotonation to yield DELTA6-protoilludene. Proposed mechanisms for sesquiterpene production by DELTA6-protoilludene synthases, overview |
747535 |
| 4.2.3.135 | (2E,6E)-farnesyl diphosphate = DELTA6-protoilludene + diphosphate |
in the presence of Ca2+, DELTA6-protoilludene synthases catalyze diverse cyclization reactions. DELTA6-Protoilludene and (E)-beta-caryophyllene result from a 1,11 cyclization of (2E,6E)-FPP following metal ion mediated ionization. The intermediate trans-humulyl cation may undergo a hydride shift followed by two cyclizations and a deprotonation to yield DELTA6-protoilludene. Proposed mechanisms for sesquiterpene production by DELTA6-protoilludene synthases, overview |
747535 |
| 4.2.3.135 | (2E,6E)-farnesyl diphosphate = DELTA6-protoilludene + diphosphate |
in the presence of Ca2+, DELTA6-protoilludene synthases catalyze diverse cyclization reactions. DELTA6-Protoilludene and (E)-beta-caryophyllene result from a 1,11-cyclization of (2E,6E)-farnesyl diphosphate following metal ion mediated ionization. The intermediate trans-humulyl cation may undergo a hydride shift followed by two cyclizations and a deprotonation to yield DELTA6-protoilludene. Proposed mechanisms for sesquiterpene production by DELTA6-protoilludene synthases, overview |
747535 |
