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Results 1 - 4 of 4
EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.114geranyl diphosphate = gamma-terpinene + diphosphate - -
Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.114geranyl diphosphate = gamma-terpinene + diphosphate ionization of geranyl diphosphate folded in left-handed helical form gives, by syn-isomerization, (3R)-linalyl diphosphate, which by rotation about C2-C3 provides the cisoid, anti-endo conformation. Ionization and cyclization of this bound intermediate yield the (4R)-alpha-terpinyl cation that, following the 1,2-hydride shift, affords the terpinen-4-yl cation. Loss of the (5S)-proton terminates the reaction to generate gamma-terpinene 701893
Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.114geranyl diphosphate = gamma-terpinene + diphosphate major products sabinene and gamma-terpinene are formed by a cyclization mechanism involving a 1,2-hydride shift in the alpha-terpinyl cation intermediate 3779
Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.114geranyl diphosphate = gamma-terpinene + diphosphate mechanism involves the cyclizazion of the acyclic precursor, loss of a proton from C5 to form the delta4 double bond, and a 1,2-hydride shift fom C4 to C8 to give gamma-terpinene 717142
Results 1 - 4 of 4