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Results 1 - 10 of 12 > >>
EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan - -
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan ability of dimethylallyltryptophan synthase to prenylate at five different sites on the indole nucleus, with normal and reverse prenylation at one of the sites, is consistent with a dissociative electrophilic alkylation of the indole ring, where orientation of the substrates within the active site and substituent electronic effects determine the position and type of prenylation 722461
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan catalytic reaction mechanism, overview 722461
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan Cope mechanism for the reaction catalyzed by DMAT synthase, overview 722452
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan enzyme-catalyzed sigmatropic process in the C-4 prenylation of indole alkaloids, an initial reverse prenylation of tryptophan at C-3 with dimethylallyl diphosphate, the subsequent Cope rearrangement shifts the prenyl moiety to the C-4 position and re-aromatization gives dimethylallyltryptophan, reaction mechanism,overview 721293
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan random sequential mechanism -, 637463
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan reaction mechanism and substrate specificity, overview 723326
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan sequential mechanism -, 637459
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan SN1-like mechanism involving a discrete carbocation intermediate involving initial ion pair formation followed by a reverse prenylation at the nucleophilic C-3 position, detailed overview 726466
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.34dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan stereochemistry, direct attack of dimethylallyl diphosphate on C-4 of the indole 637460
Results 1 - 10 of 12 > >>