EC Number   |
Reaction |
Reference |
|---|
   1.4.9.1 | methylamine + H2O + 2 amicyanin = formaldehyde + NH3 + 2 reduced amicyanin |
- |
- |
| 1.4.9.1 | methylamine + H2O + 2 amicyanin = formaldehyde + NH3 + 2 reduced amicyanin |
in the rate-determining step, a proton is transferred from the methyl group of the substrate to residue D76. Only one of the oxygen atoms of D76 can act as an acceptor of the proton, the other interacts with T122 via a strong hydrogen bond |
675610 |
| 1.4.9.1 | methylamine + H2O + 2 amicyanin = formaldehyde + NH3 + 2 reduced amicyanin |
model of electron transfer reaction between enzyme and transfer protein amicyanin |
672193 |
| 1.4.9.1 | methylamine + H2O + 2 amicyanin = formaldehyde + NH3 + 2 reduced amicyanin |
reduction of Cu2+ of electron transfer protein amicyanin by enzyme is a true electron transfer reaction |
672034 |
| 1.4.9.1 | methylamine + H2O + 2 amicyanin = formaldehyde + NH3 + 2 reduced amicyanin |
the rate-determining step in the reductive half-reaction of the bacterial enzyme methylamine dehydrogenase is the proton abstraction from the native substrate methylamine, ab initio QM/MM molecular dynamics simulations, average flow of electronic charge within the QM subsystem during proton transfer to OD1 computed from randomly selected subsets of the reactant, model comparisons, detailed overview |
742302 |
