EC Number   |
Reaction |
Reference |
|---|
   1.14.19.5 | an acyl-CoA + 2 ferrocytochrome b5 + O2 + 2 H+ = an (11Z)-enoyl-CoA + 2 ferricytochrome b5 + 2 H2O |
a single enzyme may be responsible for the formation of both (Z)- and (E)-11-tetradecanoic acids. It is also possible that two mechanistically identical discrete enzymes are involved in each desaturation |
285465 |
| 1.14.19.5 | an acyl-CoA + 2 ferrocytochrome b5 + O2 + 2 H+ = an (11Z)-enoyl-CoA + 2 ferricytochrome b5 + 2 H2O |
reaction involves a first slow, isotope-sensitive C11-H cleavage, with probable formation of an unstable intermediate, followed by a second fast C12-H bond removal |
285465 |
| 1.14.19.5 | long-chain acyl-CoA + reduced acceptor + O2 = DELTA11-acyl-CoA + acceptor + 2 H2O |
- |
- |
| 1.14.19.5 | long-chain acyl-CoA + reduced acceptor + O2 = DELTA11-acyl-CoA + acceptor + 2 H2O |
active site modeling |
674009 |
