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EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 1.13.11.412,4'-dihydroxyacetophenone + O2 = 4-hydroxybenzoate + formate - -
Display the word mapDisplay the reaction diagram Show all sequences 1.13.11.412,4'-dihydroxyacetophenone + O2 = 4-hydroxybenzoate + formate the cleavage mechanism of the aliphatic C-C bond catalyzed by 2,4'-dihydroxyacetophenone dioxygenase, quantum mechanics/molecular mechanics calculations. The reactant complex may firstly undergo a triplet-quintet crossing to initiate the reaction and then the subsequent chemistry mainly occurs on the quintet state surface, modeling of the enzyme-substrate complex, overview 742232
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