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EC Number Application Commentary Reference
Display the reaction diagram Show all sequences 4.1.2.46synthesis optically active aliphatic omega-hydroxycyanohydrins are valued materials in organic synthesis 652954
Display the reaction diagram Show all sequences 4.1.2.46synthesis production of organosilicon compounds by enantioselective transcyanation. Under optimum conditions, both acetyltrimethylsilane conversion to (R)-2-trimethylsilyl-2-hydroxy-ethylcyanide and enantiomeric excess of the product are above 99%. the silicon atom in acetyltrimethylsilane has a great effect on the eaction and both the substrate conversion and the product enantiomeric excess are much higher than those in its carbon counterpart 3,3-dimethyl-2-butanone 728212
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