1.14.12.25 indole-2-carboxylate + NADH + H+ + O2 product rearranges spontaneously forming indigo, indirubin, and isatin Pseudomonas putida 2,3-dihydroxy-2,3-dihydro-1H-indole-2-carboxylic acid + NAD+ - ? 437617 1.14.12.25 indole-3-carboxylate + NADH + H+ + O2 - Pseudomonas putida 2,3-dihydroxy-2,3-dihydro-1H-indole-3-carboxylic acid + NAD+ - ? 437618 1.14.12.25 m-toluate + NADH + H+ + O2 - Pseudomonas putida 1,6-dihydroxy-5-methylcyclohexa-2,4-diene-1-carboxylic acid + NAD+ - ? 437680 1.14.12.25 p-cumate + NADH + H+ + O2 - Pseudomonas putida 2,3-dihydroxy-2,3-dihydro-p-cumate + NAD+ - ? 436537 1.14.12.25 p-cumate + NADH + H+ + O2 - Pseudomonas putida 2,3-dihydroxy-2,3-dihydro-p-cumate + NAD+ the substrate for the ring cleavage of 2,3-dihydroxy-p-cumate is formed from p-cumate in two reactions via a dihydrodiol intermediate (2,3-dihydroxy-4-isopropylcyclohexa-4,6-dienoate). Both hydroxyl atoms of the dihydrodiol are derived from the same molecule of 02 ? 436537 1.14.12.25 p-cumate + NADH + H+ + O2 - Paraburkholderia xenovorans (2R,3S)-2,3-dihydroxy-2,3-dihydro-p-cumate + NAD+ - ? 440369