4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Trichoderma harzianum	trichodiene + diphosphate	-	?	407562	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium graminearum	trichodiene + diphosphate	-	?	407562	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium sporotrichioides	trichodiene + diphosphate	-	?	407562	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium verticillioides	trichodiene + diphosphate	biosynthesis occurs via the (R)-bisabolyl cation to the (S)-cuprenyl cation by a 1,5-proton transfer. This conversion proceeds via a 7Si,11Re cyclisation and without exchange of the migrating proton. Side products (-)-alpha-cedrene, (+)-beta-cedrene, and (+)-alpha-funebrene found in Fusarium verticillioides can originate via the (R)-bisabolyl cation	?	407562	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium verticillioides NRRL 20956	trichodiene + diphosphate	biosynthesis occurs via the (R)-bisabolyl cation to the (S)-cuprenyl cation by a 1,5-proton transfer. This conversion proceeds via a 7Si,11Re cyclisation and without exchange of the migrating proton. Side products (-)-alpha-cedrene, (+)-beta-cedrene, and (+)-alpha-funebrene found in Fusarium verticillioides can originate via the (R)-bisabolyl cation	?	407562	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium graminearum JCM9873	trichodiene + diphosphate	-	?	407562	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium sporotrichioides	trichodiene + diphosphate + isochamigrene	-	?	444076	
4.2.3.6	(2E,6E)-farnesyl diphosphate	-	Fusarium sporotrichioides DSM 62425	trichodiene + diphosphate + isochamigrene	-	?	444076	
4.2.3.6	(3R)-nerolidyl diphosphate	-	Trichothecium roseum	?	-	?	363274	
4.2.3.6	(3R)-nerolidyl diphosphate	-	Fusarium sporotrichioides	?	-	?	363274	
4.2.3.6	(7S)-6,7-dihydrofarnesyl diphosphate	-	Escherichia coli	dihydrofarnesene isomers + (E)-6,7-dihydrofarnesol + (3S,7S)-6,7-dihydronerolidol	-	?	363275	
4.2.3.6	(7S)-6,7-dihydrofarnesyl diphosphate	-	Fusarium sporotrichioides	dihydrofarnesene isomers + (E)-6,7-dihydrofarnesol + (3S,7S)-6,7-dihydronerolidol	-	?	363275	
4.2.3.6	(E,E)-farnesyl diphosphate	-	Escherichia coli	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	-	Fusarium sambucinum	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	-	Trichothecium roseum	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	-	Fusarium sporotrichioides	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	formation of trichodiene involves initial generation of (3R)-nerolidyl diphosphate	Escherichia coli	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	formation of trichodiene involves initial generation of (3R)-nerolidyl diphosphate	Trichothecium roseum	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	formation of trichodiene involves initial generation of (3R)-nerolidyl diphosphate	Fusarium sporotrichioides	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	which cyclizes via the anti-boat conformation	Trichothecium roseum	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(E,E)-farnesyl diphosphate	-	Fusarium sporotrichioides NRLL 3299	trichodiene + diphosphate	-	?	363272	
4.2.3.6	(Z,E)-farnesyl diphosphate	-	Fusarium sporotrichioides	?	-	?	363273	
4.2.3.6	2-fluorofarnesyl diphosphate	-	Fusarium sporotrichioides	?	sesquiterpene mixture	?	390642	
4.2.3.6	4-methylfarnesyl diphosphate	-	Fusarium sporotrichioides	?	sesquiterpene mixture	?	390825	
4.2.3.6	additional information	reaction proceeds via isomerization of farnesyl diphosphate to (3R)-nerolidyl diphosphate and further to trichodiene	Escherichia coli	?	-	?	89	
4.2.3.6	additional information	reaction proceeds via isomerization of farnesyl diphosphate to (3R)-nerolidyl diphosphate and further to trichodiene	Trichothecium roseum	?	-	?	89	
4.2.3.6	additional information	involved in biosynthesis of trichothecene mycotoxins	Fusarium sporotrichioides	?	-	?	89	
4.2.3.6	trans,trans-farnesyl diphosphate	-	Fusarium sporotrichioides	trichodiene + diphosphate	-	?	390332	
4.2.3.6	trans,trans-farnesyl diphosphate	the initial committing step into the trichothecene biosynthetic pathway, enzyme controls mycotoxin biosynthesis	Fusarium graminearum	trichodiene + diphosphate	-	?	390332	
4.2.3.6	trans,trans-farnesyl diphosphate	the initial committing step into the trichothecene biosynthetic pathway, enzyme controls mycotoxin biosynthesis	Fusarium graminearum PH-1	trichodiene + diphosphate	-	?	390332