1.1.99.29 2,3-didehydro-D-glucose + 1,4-benzoquinone - Chlorophyllum rhacodes 3-dehydro-D-glucose + hydroquinone - ? 424474 1.1.99.29 2,3-didehydro-D-glucose + 1,4-benzoquinone - Agaricus xanthodermus 3-dehydro-D-glucose + hydroquinone - ? 424474 1.1.99.29 2,3-didehydro-D-glucose + 1,4-benzoquinone - Leucoagaricus meleagris 3-dehydro-D-glucose + hydroquinone - ? 424474 1.1.99.29 2-dehydro-D-xylose + 1,4-benzoquinone - Chlorophyllum rhacodes 2,3-didehydro-D-xylose + hydroquinone - ? 424483 1.1.99.29 2-dehydro-D-xylose + 1,4-benzoquinone - Agaricus xanthodermus 2,3-didehydro-D-xylose + hydroquinone - ? 424483 1.1.99.29 2-dehydro-D-xylose + 1,4-benzoquinone - Leucoagaricus meleagris 2,3-didehydro-D-xylose + hydroquinone - ? 424483 1.1.99.29 2-dehydrolactose + acceptor - Agaricus xanthodermus 2,3-didehydrolactose + reduced acceptor - ? 403521 1.1.99.29 2-deoxy-D-galactose + acceptor - Leucoagaricus meleagris ? - ? 395501 1.1.99.29 2-deoxy-D-galactose + acceptor relative activity towards D-glucose (100%): 31% Leucoagaricus meleagris ? - ? 395501 1.1.99.29 2-deoxy-D-glucose + 1,4-benzoquinone 49% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 371659 1.1.99.29 2-deoxy-D-glucose + acceptor - Leucoagaricus meleagris ? - ? 395503 1.1.99.29 2-deoxy-D-glucose + acceptor relative activity towards D-glucose (100%): 27% Leucoagaricus meleagris ? - ? 395503 1.1.99.29 2-deoxy-D-glucose + ferricenium ion 21% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 371662 1.1.99.29 2-hydroxymethylphenyl-beta-D-glucopyranoside + acceptor salicin, relative activity towards D-glucose (100%): 78% Leucoagaricus meleagris ? - ? 403555 1.1.99.29 3-dehydro-D-glucose + 1,4-benzoquinone - Chlorophyllum rhacodes 2,3-didehydro-D-glucose + hydroquinone - ? 371830 1.1.99.29 3-fluoro-3-deoxy-D-glucose + acceptor - Leucoagaricus meleagris ? + reduced acceptor - ? 425551 1.1.99.29 4-hydroxyphenyl-beta-D-glucopyranoside + acceptor arbutin Leucoagaricus meleagris ? - ? 403860 1.1.99.29 6-deoxy-D-glucose + acceptor relative activity towards D-glucose (100%): 105% Leucoagaricus meleagris ? - ? 404061 1.1.99.29 a pyranoside + acceptor - Agaricus bisporus a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor - ? 359220 1.1.99.29 a pyranoside + acceptor - Chlorophyllum rhacodes a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor - ? 359220 1.1.99.29 a pyranoside + acceptor - Agaricus bisporus U3 a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor - ? 359220 1.1.99.29 a pyranoside + acceptor - Agaricus bisporus 306 a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor - ? 359220 1.1.99.29 a pyranoside + acceptor - Agaricus bisporus 3,4-didehydropyranoside + reduced acceptor - ? 404122 1.1.99.29 a pyranoside + acceptor - Chlorophyllum rhacodes a 3,4-didehydropyranoside + reduced acceptor - ? 404123 1.1.99.29 a pyranoside + acceptor - Agaricus xanthodermus a 3,4-didehydropyranoside + reduced acceptor - ? 404123 1.1.99.29 a pyranoside + acceptor - Leucoagaricus meleagris a 3,4-didehydropyranoside + reduced acceptor - ? 404123 1.1.99.29 a pyranoside + acceptor - Chlorophyllum rhacodes a 3-dehydropyranoside + reduced acceptor - ? 404124 1.1.99.29 a pyranoside + acceptor - Agaricus xanthodermus a 3-dehydropyranoside + reduced acceptor - ? 404124 1.1.99.29 a pyranoside + acceptor - Leucoagaricus meleagris a 3-dehydropyranoside + reduced acceptor - ? 404124 1.1.99.29 a pyranoside + acceptor - Agaricus bisporus a 3-dehydropyranoside + reduced acceptor - ? 404124 1.1.99.29 a pyranoside + acceptor - Leucoagaricus meleagris a 3-dehydropyranoside + reduced acceptor 3-dehydropyranoside or 3,4-didehydropyranoside ? 404124 1.1.99.29 aldopyranose + 1,4-benzoquinone more active as electron acceptor than 2,6-dichlorophenolindophenol or ferricyanide, less active than 3,5-di-tert-butyl-1,2-benzoquinone, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses Agaricus bisporus 2-aldoketose + hydroquinone - ? 372283 1.1.99.29 aldopyranose + 2,6-dichlorophenolindophenol 65.9% of the activity with 1,4-benzoquinone as electron acceptor, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses Agaricus bisporus 2-aldoketose + reduced 2,6-dichlorophenolindophenol - ? 372284 1.1.99.29 aldopyranose + 3,5-di-tert-butyl-1,2-benzoquinone - Agaricus xanthodermus 2-aldoketose + reduced 3,5-di-tert-butyl-1,2-benzoquinone - ? 372285 1.1.99.29 aldopyranose + 3,5-di-tert-butyl-1,2-benzoquinone 4.3fold higher activity than with 1,4-benzoquinone as electron acceptor, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses Agaricus bisporus 2-aldoketose + reduced 3,5-di-tert-butyl-1,2-benzoquinone - ? 372285 1.1.99.29 aldopyranose + ferricyanide 10.4% of the activity with 1,4-benzoquinone as electron acceptor, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses Agaricus bisporus 2-aldoketose + ferrocyanide - ? 372286 1.1.99.29 aldopyranose + quinone C-2 specific sugar oxidoreductase, highly nonspecific, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses Agaricus bisporus 2-aldoketose + hydroquinone - ? 372287 1.1.99.29 alpha,alpha-trehalose + 1,4-benzoquinone quinone-dependent PDH oxidizes alpha,alpha-trehalose at C-3 and C-3’, 5% of the activity with D-glucose Leucoagaricus meleagris 3,3'-didehydro-alpha,alpha-trehalose + hydroquinone with 3-dehydro-alpha,alpha-trehalose as reaction intermediate ? 372296 1.1.99.29 alpha,alpha-trehalose + 1,4-benzoquinone quinone-dependent PDH oxidizes alpha,alpha-trehalose at C-3 and C-3’, 5% of the activity with D-glucose Leucoagaricus meleagris CCBAS 907 3,3'-didehydro-alpha,alpha-trehalose + hydroquinone with 3-dehydro-alpha,alpha-trehalose as reaction intermediate ? 372296 1.1.99.29 alpha,alpha-trehalose + acceptor relative activity towards D-glucose (100%): 27% Leucoagaricus meleagris 3,3'-didehydro-alpha,alpha-trehalose + reduced acceptor - ? 406804 1.1.99.29 beta-lactose + acceptor - Leucoagaricus meleagris ? - ? 396605 1.1.99.29 beta-lactose + ferricenium hexafluorophosphate - Agaricus xanthodermus ? - ? 396604 1.1.99.29 cellobiitol + acceptor relative activity towards D-glucose (100%): 77% Leucoagaricus meleagris ? - ? 404634 1.1.99.29 cellobiose + 1,4-benzoquinone 13% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372631 1.1.99.29 cellobiose + 1,4-benzoquinone 94% of the activity with D-glucose Agaricus bisporus ? - ? 372631 1.1.99.29 cellobiose + 2,6-dichlorophenolindophenol - Leucoagaricus meleagris 2-dehydro-cellobiose + reduced 2,6-dichlorophenolindophenol - ? 439288 1.1.99.29 cellobiose + acceptor relative activity towards D-glucose (100%): 70% Leucoagaricus meleagris ? - ? 257773 1.1.99.29 cellobiose + Fe3+ - Leucoagaricus meleagris ? - ? 396676 1.1.99.29 cellobiose + ferricenium ion 7% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372637 1.1.99.29 cellobiose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424699 1.1.99.29 cellobiose + ferrocenium ion - Leucoagaricus meleagris 2-dehydro-cellobiose + ferrocene - ? 439293 1.1.99.29 cellobiose + ferrocenium ion - Agaricus bisporus 2-dehydro-cellobiose + ferrocene - ? 439293 1.1.99.29 cellobiose + ferrocenium ion - Agaricus bisporus DSM 3056 2-dehydro-cellobiose + ferrocene - ? 439293 1.1.99.29 cellotetraose + acceptor relative activity towards D-glucose (100%): 14% Leucoagaricus meleagris ? - ? 396681 1.1.99.29 cellotriose + 1,4-benzoquinone 56% of the activity with D-glucose Agaricus bisporus ? - ? 372660 1.1.99.29 D-allose + 1,4-benzoquinone 30% of the activity with D-glucose Agaricus bisporus 2-dehydro-D-allose + hydroquinone - ? 372816 1.1.99.29 D-allose + acceptor relative activity towards D-glucose (100%): 15% Leucoagaricus meleagris ? - ? 404770 1.1.99.29 D-allose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 439375 1.1.99.29 D-arabino-2-hexosulose + 1,4-benzoquinone 59% of the activity with D-glucose Agaricus bisporus ? - ? 372821 1.1.99.29 D-arabinose + 1,4-benzoquinone 18% of the activity with D-glucose Agaricus bisporus 2-dehydro-D-arabinose + hydroquinone - ? 372823 1.1.99.29 D-arabinose + ferricenium hexafluorophosphate - Agaricus xanthodermus ? - ? 396837 1.1.99.29 D-cellobiose + acceptor - Leucoagaricus meleagris ? - ? 396847 1.1.99.29 D-fructose + acceptor - Leucoagaricus meleagris ? - ? 404796 1.1.99.29 D-fructose + Fe3+ - Leucoagaricus meleagris ? - ? 396850 1.1.99.29 D-fructose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424742 1.1.99.29 D-galactose + 1,4-benzoquinone 88% of the activity with D-glucose Agaricus bisporus 2-dehydro-D-galactose + hydroquinone - ? 372852 1.1.99.29 D-galactose + 1,4-benzoquinone PDH oxidizes D-galactose exclusively at C-2 to produce D-lyxo-hexos-2-ulose Agaricus bisporus 2-dehydro-D-galactose + hydroquinone 2-keto-D-galactose ? 372852 1.1.99.29 D-galactose + 1,4-benzoquinone quinone-dependent PDH oxidizes D-galactose exclusively at C-2 Agaricus bisporus 2-dehydro-D-galactose + hydroquinone - ? 372852 1.1.99.29 D-galactose + 1,4-benzoquinone PDH oxidizes D-galactose exclusively at C-2 to produce D-lyxo-hexos-2-ulose Agaricus bisporus U3 2-dehydro-D-galactose + hydroquinone 2-keto-D-galactose ? 372852 1.1.99.29 D-galactose + 1,4-benzoquinone quinone-dependent PDH oxidizes D-galactose exclusively at C-2 Agaricus bisporus 306 2-dehydro-D-galactose + hydroquinone - ? 372852 1.1.99.29 D-galactose + 1,4-benzoquinone 66% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372853 1.1.99.29 D-galactose + acceptor - Leucoagaricus meleagris ? - ? 396855 1.1.99.29 D-galactose + acceptor relative activity towards D-glucase (100%): 99% Leucoagaricus meleagris 2-dehydro-D-galactose + reduced acceptor - ? 406634 1.1.99.29 D-galactose + benzoquinone - Agaricus xanthodermus 2,3-didehydro-D-galactose + hydroquinone two main reaction products ? 396856 1.1.99.29 D-galactose + benzoquinone - Leucoagaricus meleagris 2-dehydro-D-galactose + hydroquinone no 2,3-didehydro-d-galactose is detectable ? 396857 1.1.99.29 D-galactose + benzoquinone - Agaricus xanthodermus 2-dehydro-D-galactose + hydroquinone two main reaction products ? 396857 1.1.99.29 D-galactose + Fe3+ - Leucoagaricus meleagris 2-dehydro-D-galactose + Fe2+ + H+ - ? 396858 1.1.99.29 D-galactose + ferricenium ion 60% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372855 1.1.99.29 D-galactose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 414484 1.1.99.29 D-galactose + ferricenium ion - Leucoagaricus meleagris CCBAS 907 ? + ferrocene - ? 414484 1.1.99.29 D-galactose + ferrocenium ion - Leucoagaricus meleagris 2-dehydro-D-galactose + ferrocene - ? 424743 1.1.99.29 D-galactose + ferrocenium ion - Agaricus bisporus 2-dehydro-D-galactose + ferrocene - ? 424743 1.1.99.29 D-galactose + ferrocenium ion - Agaricus xanthodermus 2-dehydro-D-galactose + ferrocene - ? 424743 1.1.99.29 D-galactose + ferrocenium ion - Agaricus campestris 2-dehydro-D-galactose + ferrocene - ? 424743 1.1.99.29 D-galactose + ferrocenium ion - Agaricus bisporus DSM 3056 2-dehydro-D-galactose + ferrocene - ? 424743 1.1.99.29 D-glucono-1,5-lactone + 1,4-benzoquinone 20% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372874 1.1.99.29 D-glucono-1,5-lactone + 1,4-benzoquinone 118% of the activity with D-glucose Agaricus bisporus ? - ? 372874 1.1.99.29 D-glucono-1,5-lactone + acceptor relative activity towards D-glucose (100%): 42% Leucoagaricus meleagris ? - ? 404817 1.1.99.29 D-glucono-1,5-lactone + ferricenium ion 8% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372875 1.1.99.29 D-glucosamine + acceptor - Leucoagaricus meleagris ? - ? 396861 1.1.99.29 D-glucose pH 8.5 Leucoagaricus meleagris 3-dehydro-D-glucose + Fe2+ + H+ - ? 396878 1.1.99.29 D-glucose + 1,4-benzoquinone - Agaricus bisporus 2-dehydro-D-glucose + hydroquinone - ? 372878 1.1.99.29 D-glucose + 1,4-benzoquinone - Agaricus bisporus 2-dehydro-D-glucose + hydroquinone D-arabino-2-hexosulose, 2-ketoglucose ? 372878 1.1.99.29 D-glucose + 1,4-benzoquinone - Agaricus bisporus DSM 3056 2-dehydro-D-glucose + hydroquinone - ? 372878 1.1.99.29 D-glucose + 1,4-benzoquinone oxidizes D-glucose exclusively at C-3, D-glucose is the preferred electron donor susbtrate Chlorophyllum rhacodes 3-dehydro-D-glucose + hydroquinone - ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone PDH catalyzes the C-2 and C-3 oxidation of D-glucose, quinone-dependent Agaricus bisporus 3-dehydro-D-glucose + hydroquinone or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose, products are 2-keto-D-glucose and, preferentially, 3-keto-D-glucose, both are subsequently oxidized by PDH to 2,3-diketo-D-glucose ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone quinone-dependent PDH catalyzes C-2 or, preferentially, C-3 dehydrogenation of D-glucose Agaricus bisporus 3-dehydro-D-glucose + hydroquinone or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone simultaneous C-2 and C-3 oxidation of free D-glucose Leucoagaricus meleagris 3-dehydro-D-glucose + hydroquinone or 2-dehydro-D-glucose ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone PDH catalyzes the C-2 and C-3 oxidation of D-glucose, quinone-dependent Agaricus bisporus U3 3-dehydro-D-glucose + hydroquinone or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose, products are 2-keto-D-glucose and, preferentially, 3-keto-D-glucose, both are subsequently oxidized by PDH to 2,3-diketo-D-glucose ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone quinone-dependent PDH catalyzes C-2 or, preferentially, C-3 dehydrogenation of D-glucose Agaricus bisporus 306 3-dehydro-D-glucose + hydroquinone or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone simultaneous C-2 and C-3 oxidation of free D-glucose Leucoagaricus meleagris CCBAS 907 3-dehydro-D-glucose + hydroquinone or 2-dehydro-D-glucose ? 372879 1.1.99.29 D-glucose + 1,4-benzoquinone - Leucoagaricus meleagris ? - ? 414486 1.1.99.29 D-glucose + 1,4-benzoquinone - Leucoagaricus meleagris CCBAS 907 ? - ? 414486 1.1.99.29 D-glucose + 1,4-benzoquinone - Chlorophyllum rhacodes 2,3-didehydro-D-glucose + hydroquinone - ? 424746 1.1.99.29 D-glucose + 1,4-benzoquinone - Agaricus xanthodermus 2,3-didehydro-D-glucose + hydroquinone - ? 424746 1.1.99.29 D-glucose + 1,4-benzoquinone - Leucoagaricus meleagris 2,3-didehydro-D-glucose + hydroquinone - ? 424746 1.1.99.29 D-glucose + 1,4-benzoquinone - Leucoagaricus meleagris 2-dehydro-D-glucose + ? - ? 439407 1.1.99.29 D-glucose + 1,4-benzoquinone - Agaricus xanthodermus 2-dehydro-D-glucose + ? - ? 439407 1.1.99.29 D-glucose + 1,4-benzoquinone - Agaricus campestris 2-dehydro-D-glucose + ? - ? 439407 1.1.99.29 D-glucose + 2 1,4-benzoquinone - Chlorophyllum rhacodes 2,3-didehydro-D-glucose + 2 hydroquinone - ? 404820 1.1.99.29 D-glucose + 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) - Agaricus bisporus 2-dehydro-D-glucose + reduced 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) - ? 439408 1.1.99.29 D-glucose + 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) - Agaricus bisporus DSM 3056 2-dehydro-D-glucose + reduced 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) - ? 439408 1.1.99.29 D-glucose + 2,2'-azino-bis[3-ethylbenzothiazoline]-6-sulfonic acid - Leucoagaricus meleagris 2-dehydro-D-glucose + ? - ? 439409 1.1.99.29 D-glucose + 2,2'-azino-bis[3-ethylbenzothiazoline]-6-sulfonic acid - Leucoagaricus meleagris 3-dehydro-D-glucose + ? - ? 439410 1.1.99.29 D-glucose + 2,5-chloro-1,4-benzoquinone pH 5 Leucoagaricus meleagris ? - ? 396862 1.1.99.29 D-glucose + 2,6-dichloroindophenol - Agaricus xanthodermus ? - ? 396863 1.1.99.29 D-glucose + 2,6-dichloroindophenol pH 4 Leucoagaricus meleagris ? - ? 396863 1.1.99.29 D-glucose + 2,6-dichlorophenolindophenol - Leucoagaricus meleagris 2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol - ? 188904 1.1.99.29 D-glucose + 2,6-dichlorophenolindophenol - Agaricus bisporus 2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol - ? 188904 1.1.99.29 D-glucose + 2,6-dichlorophenolindophenol - Agaricus xanthodermus 2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol - ? 188904 1.1.99.29 D-glucose + 2,6-dichlorophenolindophenol - Agaricus campestris 2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol - ? 188904 1.1.99.29 D-glucose + 2,6-dichlorophenolindophenol - Agaricus bisporus DSM 3056 2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol - ? 188904 1.1.99.29 D-glucose + 2-(hydroxymethyl)-6-methoxy-1,4-benzoquinone - Agaricus xanthodermus ? - ? 396864 1.1.99.29 D-glucose + 2-chloro-1,4-benzoquinone - Agaricus xanthodermus ? - ? 396866 1.1.99.29 D-glucose + 2-chloro-1,4-benzoquinone - Leucoagaricus meleagris ? - ? 396866 1.1.99.29 D-glucose + 2-chloro-1,4-benzoquinone pH 5 Leucoagaricus meleagris ? - ? 396866 1.1.99.29 D-glucose + 2-chloro-1,4-benzoquinone - Leucoagaricus meleagris CCBAS 907 ? - ? 396866 1.1.99.29 D-glucose + 3,5-di-t-butyl-1,2-benzoquinone - Agaricus xanthodermus ? - ? 396865 1.1.99.29 D-glucose + 3,5-di-tert-butyl-1,4-benzoquinone pH 6 Leucoagaricus meleagris ? - ? 396867 1.1.99.29 D-glucose + 3-ethylbenzthiazolin-6-sulfonic acid cation radical - Agaricus xanthodermus ? - ? 396868 1.1.99.29 D-glucose + acceptor - Leucoagaricus meleagris 3-dehydro-D-glucose + reduced acceptor - ? 388448 1.1.99.29 D-glucose + acceptor - Agaricus xanthodermus 3-dehydro-D-glucose + reduced acceptor - ? 388448 1.1.99.29 D-glucose + acceptor relative activity towards D-glucose (100%): 100% Leucoagaricus meleagris ? - ? 404824 1.1.99.29 D-glucose + acceptor dioxidation at C2 and C3 Leucoagaricus meleagris 2,3-didehydro-D-glucose + reduced acceptor - ? 424750 1.1.99.29 D-glucose + acceptor - Leucoagaricus meleagris 2-dehydro-D-glucose + reduced acceptor - ? 424751 1.1.99.29 D-glucose + acceptor the enzyme oxidizes D-glucose at both the C2 and C3 position but the C2 position is the primary site of attack Leucoagaricus meleagris 2-dehydro-D-glucose + reduced acceptor - ? 424751 1.1.99.29 D-glucose + benzoquinone 3-oxo-D-glucose, 1-alpha-3-dehydro-d-glucopyranose, 1-beta-3-dehydro-d-glucopyranose, 1-alpha-3-dehydro-d-glucopyranose hydrate, 1-beta-3-dehydro-d-glucopyranose hydrate, 2-dehydro-d-glucose, 1-alpha-2,3-bis-dehydro-d-glucopyranose bis-hydrate as minor reaction products Agaricus xanthodermus 2,3-didehydro-D-glucose + hydroquinone - ? 396869 1.1.99.29 D-glucose + benzoquinone pH 3 Leucoagaricus meleagris 2,3-didehydro-D-glucose + hydroquinone - ? 396869 1.1.99.29 D-glucose + CuSO4 - Agaricus xanthodermus ? - ? 396870 1.1.99.29 D-glucose + dimethylaminomethyl-ferricenium - Agaricus xanthodermus ? - ? 396871 1.1.99.29 D-glucose + Fe3+ - Agaricus xanthodermus 3-dehydro-D-glucose + Fe2+ + H+ - ? 396872 1.1.99.29 D-glucose + ferricenium ion - Chlorophyllum rhacodes 3-dehydro-D-glucose + ferrocene - ? 372892 1.1.99.29 D-glucose + ferricenium ion - Agaricus xanthodermus 3-dehydro-D-glucose + ferrocene - ? 372892 1.1.99.29 D-glucose + ferricenium ion - Leucoagaricus meleagris 3-dehydro-D-glucose + ferrocene - ? 372892 1.1.99.29 D-glucose + ferricenium ion oxidizes D-glucose exclusively at C-3, D-glucose is the preferred electron donor susbtrate Chlorophyllum rhacodes 3-dehydro-D-glucose + ferrocene - ? 372892 1.1.99.29 D-glucose + ferricenium ion - Leucoagaricus meleagris CCBAS 907 3-dehydro-D-glucose + ferrocene - ? 372892 1.1.99.29 D-glucose + ferricenium ion - Leucoagaricus meleagris 2-dehydro-D-glucose + ferrocene - ? 439416 1.1.99.29 D-glucose + ferricyanide - Agaricus xanthodermus ? - ? 396873 1.1.99.29 D-glucose + ferrocenium ion - Leucoagaricus meleagris 3-dehydro-D-glucose + ferrocene - ? 424754 1.1.99.29 D-glucose + ferrocenium ion - Leucoagaricus meleagris 2-dehydro-D-glucose + ferrocene - ? 439418 1.1.99.29 D-glucose + ferrocenium ion - Agaricus xanthodermus 2-dehydro-D-glucose + ferrocene - ? 439418 1.1.99.29 D-glucose + ferrocenium ion - Agaricus campestris 2-dehydro-D-glucose + ferrocene - ? 439418 1.1.99.29 D-glucose + ferrocenium ion ferrocenium ion is the preferred electron acceptor Agaricus bisporus 2-dehydro-D-glucose + ferrocene - ? 439418 1.1.99.29 D-glucose + methyl-1,4-benzoquinone - Agaricus xanthodermus ? - ? 396874 1.1.99.29 D-glucose + methyl-1,4-benzoquinone pH 8 Leucoagaricus meleagris ? - ? 396874 1.1.99.29 D-glucose + O2 - Leucoagaricus meleagris 2-dehydro-D-glucose + H2O2 - ? 257397 1.1.99.29 D-glucose + tetrachloro-1,4-benzoquinone - Agaricus xanthodermus ? - ? 396876 1.1.99.29 D-glucose + tetrafluoro-1,4-benzoquinone - Agaricus xanthodermus ? - ? 396877 1.1.99.29 D-gulose + acceptor relative activity towards D-glucose (100%): 7% Leucoagaricus meleagris ? - ? 404844 1.1.99.29 D-lyxose + 1,4-benzoquinone 5% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372939 1.1.99.29 D-lyxose + ferricenium ion 5% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372940 1.1.99.29 D-maltoheptaose + acceptor - Leucoagaricus meleagris ? - ? 396900 1.1.99.29 D-maltopentaose + acceptor - Leucoagaricus meleagris ? - ? 396902 1.1.99.29 D-maltose + acceptor - Leucoagaricus meleagris ? - ? 396903 1.1.99.29 D-maltose + acceptor relative activity towards D-glucose (100%): 61% Leucoagaricus meleagris ? - ? 396903 1.1.99.29 D-maltose + Fe3+ - Leucoagaricus meleagris ? - ? 396904 1.1.99.29 D-maltose + ferricenium hexafluorophosphate - Agaricus xanthodermus ? - ? 396905 1.1.99.29 D-maltose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424760 1.1.99.29 D-maltotriose + acceptor - Leucoagaricus meleagris ? - ? 396911 1.1.99.29 D-maltotriose + Fe3+ - Leucoagaricus meleagris ? - ? 396908 1.1.99.29 D-maltotriose + ferricenium hexafluorophosphate - Agaricus xanthodermus ? - ? 396909 1.1.99.29 D-mannose + 1,4-benzoquinone 32% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372949 1.1.99.29 D-mannose + acceptor - Leucoagaricus meleagris ? - ? 396914 1.1.99.29 D-mannose + acceptor relative activity towards D-glucose (100%): 24% Leucoagaricus meleagris ? - ? 396914 1.1.99.29 D-mannose + acceptor - Leucoagaricus meleagris 2-dehydro-D-mannose + reduced acceptor - ? 439444 1.1.99.29 D-mannose + Fe3+ - Leucoagaricus meleagris ? - ? 396913 1.1.99.29 D-mannose + ferricenium ion 26% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372951 1.1.99.29 D-mannose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424761 1.1.99.29 D-mannose + ferrocenium ion - Leucoagaricus meleagris 2-dehydro-D-mannose + ferrocene - ? 439445 1.1.99.29 D-mannose + ferrocenium ion - Agaricus bisporus 2-dehydro-D-mannose + ferrocene - ? 439445 1.1.99.29 D-ribose + 1,4-benzoquinone 34% of the activity with D-glucose Agaricus bisporus 2-dehydro-D-ribose + hydroquinone - ? 372969 1.1.99.29 D-ribose + acceptor relative activity towards D-glucose (100%): 19% Leucoagaricus meleagris ? - ? 404899 1.1.99.29 D-ribose + Fe3+ - Leucoagaricus meleagris ? - ? 396930 1.1.99.29 D-ribose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424763 1.1.99.29 D-ribulose + acceptor relative activity towards D-glucose (100%): 17% Leucoagaricus meleagris ? - ? 404903 1.1.99.29 D-sorbose + acceptor - Leucoagaricus meleagris ? - ? 404913 1.1.99.29 D-tagatose + acceptor relative activity towards D-glucoase (100%): 67% Leucoagaricus meleagris ? - ? 404914 1.1.99.29 D-talose + acceptor relative activity towards D-glucose (100%): 10% Leucoagaricus meleagris ? - ? 404917 1.1.99.29 D-talose + Fe3+ - Leucoagaricus meleagris ? - ? 396937 1.1.99.29 D-talose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424764 1.1.99.29 D-trehalose + acceptor - Leucoagaricus meleagris ? - ? 396940 1.1.99.29 D-xylose + 1,4-benzoquinone - Chlorophyllum rhacodes 2-dehydro-D-xylose + hydroquinone - ? 372990 1.1.99.29 D-xylose + 1,4-benzoquinone - Agaricus xanthodermus 2-dehydro-D-xylose + hydroquinone - ? 372990 1.1.99.29 D-xylose + 1,4-benzoquinone - Leucoagaricus meleagris 2-dehydro-D-xylose + hydroquinone - ? 372990 1.1.99.29 D-xylose + 1,4-benzoquinone 116% of the activity with D-glucose Agaricus bisporus 2-dehydro-D-xylose + hydroquinone - ? 372990 1.1.99.29 D-xylose + 1,4-benzoquinone quinone-dependent PDH oxidizes D-xylose at C-2 to 2-keto-D-xylose and successively at C-3 to 2,3-diketo-D-xylose Agaricus bisporus 2-dehydro-D-xylose + hydroquinone or 2,3-didehydro-D-xylose ? 372990 1.1.99.29 D-xylose + 1,4-benzoquinone quinone-dependent PDH oxidizes D-xylose at C-2 to 2-keto-D-xylose and successively at C-3 to 2,3-diketo-D-xylose Agaricus bisporus 306 2-dehydro-D-xylose + hydroquinone or 2,3-didehydro-D-xylose ? 372990 1.1.99.29 D-xylose + 1,4-benzoquinone 72% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372991 1.1.99.29 D-xylose + 2 1,4-benzoquinone - Agaricus bisporus 2,3-didehydro-D-xylose + 2 hydroquinone - ? 404927 1.1.99.29 D-xylose + acceptor - Leucoagaricus meleagris ? - ? 257805 1.1.99.29 D-xylose + acceptor relative activity towards D-glucose (100%): 113% Leucoagaricus meleagris ? - ? 257805 1.1.99.29 D-xylose + Fe3+ - Leucoagaricus meleagris ? - ? 396952 1.1.99.29 D-xylose + ferricenium hexafluorophosphate - Agaricus xanthodermus ? - ? 396953 1.1.99.29 D-xylose + ferricenium ion 81% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 372993 1.1.99.29 D-xylose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 414519 1.1.99.29 D-xylose + ferricenium ion - Leucoagaricus meleagris CCBAS 907 ? + ferrocene - ? 414519 1.1.99.29 D-xylose + ferrocenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424767 1.1.99.29 D-xylose + ferrocenium ion - Agaricus bisporus 2-dehydro-D-xylose + ferrocene - ? 439471 1.1.99.29 D-xylose + ferrocenium ion - Agaricus xanthodermus 2-dehydro-D-xylose + ferrocene - ? 439471 1.1.99.29 D-xylose + ferrocenium ion - Agaricus campestris 2-dehydro-D-xylose + ferrocene - ? 439471 1.1.99.29 erlose + 1,4-benzoquinone quinone-dependent PDH oxidizes erlose at exclusively C-3 of its terminal glucopyranosyl moiety, 9% of the activity with D-glucose Leucoagaricus meleagris 3-dehydroerlose + hydroquinone - ? 373157 1.1.99.29 erlose + 1,4-benzoquinone quinone-dependent PDH oxidizes erlose at exclusively C-3 of its terminal glucopyranosyl moiety, 9% of the activity with D-glucose Leucoagaricus meleagris CCBAS 907 3-dehydroerlose + hydroquinone - ? 373157 1.1.99.29 gentiobiose + ferricenium hexafluorophosphate - Agaricus xanthodermus ? - ? 397250 1.1.99.29 L-arabinose + 1,4-benzoquinone 113% of the activity with D-glucose Agaricus bisporus 2-dehydro-L-arabinose + hydroquinone - ? 373542 1.1.99.29 L-arabinose + 1,4-benzoquinone 54% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373543 1.1.99.29 L-arabinose + acceptor - Leucoagaricus meleagris ? - ? 257804 1.1.99.29 L-arabinose + acceptor relative activity towards D-glucose (100%): 100% Leucoagaricus meleagris ? - ? 257804 1.1.99.29 L-arabinose + Fe3+ - Leucoagaricus meleagris ? - ? 397545 1.1.99.29 L-arabinose + ferricenium ion 72% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373544 1.1.99.29 L-arabinose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 414744 1.1.99.29 L-arabinose + ferrocenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424845 1.1.99.29 L-arabinose + ferrocenium ion - Agaricus bisporus 2-dehydro-L-arabinose + ferrocene - ? 439642 1.1.99.29 L-arabinose + ferrocenium ion - Agaricus xanthodermus 2-dehydro-L-arabinose + ferrocene - ? 439642 1.1.99.29 L-arabinose + ferrocenium ion - Agaricus campestris 2-dehydro-L-arabinose + ferrocene - ? 439642 1.1.99.29 L-fucose + acceptor - Leucoagaricus meleagris ? - ? 397580 1.1.99.29 L-fucose + acceptor relative activity towards D-glucose (100%): 7% Leucoagaricus meleagris ? - ? 397580 1.1.99.29 L-glucose + 1,4-benzoquinone 61% of the activity with D-glucose Agaricus bisporus 2-dehydro-L-glucose + hydroquinone - ? 373582 1.1.99.29 L-glucose + acceptor relative activity towards D-glucose (100%): 42% Leucoagaricus meleagris ? - ? 405591 1.1.99.29 L-glucose + ferricenium ion 11% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373583 1.1.99.29 L-sorbose + 1,4-benzoquinone 10% of the activity with D-glucose Agaricus bisporus 2-dehydro-L-sorbose + hydroquinone - ? 373634 1.1.99.29 L-sorbose + acceptor relative activity towards D-glucose (100%): 5% Leucoagaricus meleagris ? - ? 405652 1.1.99.29 L-sorbose + Fe3+ - Leucoagaricus meleagris ? - ? 397661 1.1.99.29 L-sorbose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424877 1.1.99.29 L-xylobiose + Fe3+ - Leucoagaricus meleagris ? - ? 397679 1.1.99.29 lactose + 1,4-benzoquinone 21% of the activity with D-glucose Agaricus bisporus ? - ? 373664 1.1.99.29 lactose + acceptor relative activity towards D-glucose (100%): 15% Leucoagaricus meleagris ? - ? 257774 1.1.99.29 lactose + acceptor - Agaricus xanthodermus 2-dehydrolactose + reduced acceptor - ? 405683 1.1.99.29 lactose + acceptor - Agaricus xanthodermus lactobiono-1,5-lactone + reduced acceptor - ? 405685 1.1.99.29 lactose + acceptor - Chlorophyllum rhacodes lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor - ? 424882 1.1.99.29 lactose + acceptor - Agaricus xanthodermus lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor - ? 424882 1.1.99.29 lactose + acceptor - Leucoagaricus meleagris lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor - ? 424882 1.1.99.29 lactose + Fe3+ - Leucoagaricus meleagris ? - ? 397686 1.1.99.29 lactose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 414795 1.1.99.29 lactose + ferrocenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424883 1.1.99.29 lactose + ferrocenium ion 48% of the lactose is converted and yields 88% lactobionic acid and 12% 2-dehydrolactose Agaricus campestris ? + ferrocene - ? 424883 1.1.99.29 lactose + ferrocenium ion the enzyme converts lactose to nearly 100%, producing 69% lactobionic acid and 31% 2-dehydrolactose Agaricus xanthodermus ? + ferrocene - ? 424883 1.1.99.29 lactose + ferrocenium ion - Agaricus bisporus 2-dehydro-lactose + ferrocene - ? 439705 1.1.99.29 maltose + 1,4-benzoquinone 64% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373761 1.1.99.29 maltose + 1,4-benzoquinone 93% of the activity with D-glucose Agaricus bisporus ? - ? 373761 1.1.99.29 maltose + ferricenium ion 45% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373763 1.1.99.29 maltose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 439724 1.1.99.29 maltose + ferrocenium ion - Agaricus bisporus 2-dehydro-maltose + ferrocene - ? 439725 1.1.99.29 maltotetraose + acceptor relative activity towards D-glucose (100%): 9% Leucoagaricus meleagris ? - ? 405775 1.1.99.29 maltotriose + 1,4-benzoquinone 70% of the activity with D-glucose Agaricus bisporus ? - ? 373771 1.1.99.29 maltotriose + 1,4-benzoquinone 21% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373771 1.1.99.29 maltotriose + acceptor relative activity towards D-glucose (100%): 12% Leucoagaricus meleagris ? - ? 405777 1.1.99.29 maltotriose + ferricenium ion 14% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373772 1.1.99.29 maltotriose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 424901 1.1.99.29 melezitose + acceptor relative activity towards D-glucose (100%): 13% Leucoagaricus meleagris ? - ? 257795 1.1.99.29 melibiose + acceptor relative activity towards D-glucose (100%): 48% Leucoagaricus meleagris ? - ? 405807 1.1.99.29 melizitose + 1,4-benzoquinone quinone-dependent PDH oxidizes melezitose exclusively at C-3 of its terminal glucopyranosyl moiety, 7% of the activity with D-glucose Leucoagaricus meleagris 3-dehydromelizitose + hydroquinone - ? 373802 1.1.99.29 melizitose + 1,4-benzoquinone quinone-dependent PDH oxidizes melezitose exclusively at C-3 of its terminal glucopyranosyl moiety, 7% of the activity with D-glucose Leucoagaricus meleagris CCBAS 907 3-dehydromelizitose + hydroquinone - ? 373802 1.1.99.29 methyl alpha-D-glucopyranoside + acceptor relative activity towards D-glucose (100%): 107% Leucoagaricus meleagris ? - ? 405852 1.1.99.29 methyl alpha-D-mannopyranoside + acceptor relative activity towards D-glucose (100%): 5% Leucoagaricus meleagris ? - ? 405853 1.1.99.29 methyl beta-D-glucopyranoside + acceptor relative activity towards D-glucose (100%): 58% Leucoagaricus meleagris ? - ? 405854 1.1.99.29 methyl-alpha-D-galactopyranose + acceptor relative activity towards D-glucose (100%): 17% Leucoagaricus meleagris ? - ? 405851 1.1.99.29 methyl-alpha-D-galactopyranoside + 1,4-benzoquinone 11% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373823 1.1.99.29 methyl-alpha-D-galactopyranoside + 1,4-benzoquinone 23% of the activity with D-glucose Agaricus bisporus methyl-alpha-3-dehydro-D-galactopyranoside + hydroquinone - ? 373824 1.1.99.29 methyl-alpha-D-galactopyranoside + 1,4-benzoquinone formation of the C-3 carbonyl derivative, 7% of the activity with D-glucose Leucoagaricus meleagris methyl-alpha-3-dehydro-D-galactopyranoside + hydroquinone - ? 373824 1.1.99.29 methyl-alpha-D-galactopyranoside + ferricenium ion 8% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373825 1.1.99.29 methyl-alpha-D-glucopyranoside + 1,4-benzoquinone 141% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373826 1.1.99.29 methyl-alpha-D-glucopyranoside + 1,4-benzoquinone 117% of the activity with D-glucose Agaricus bisporus methyl-alpha-3-dehydro-D-glucopyranoside + hydroquinone - ? 373827 1.1.99.29 methyl-alpha-D-glucopyranoside + 1,4-benzoquinone formation of the C-3 carbonyl derivative, 126% of the activity with D-glucose Leucoagaricus meleagris methyl-alpha-3-dehydro-D-glucopyranoside + hydroquinone - ? 373827 1.1.99.29 methyl-alpha-D-glucopyranoside + ferricenium ion 143% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373828 1.1.99.29 methyl-alpha-D-glucopyranoside + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 439751 1.1.99.29 methyl-beta-D-glucopyranoside + 1,4-benzoquinone 30% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373830 1.1.99.29 methyl-beta-D-glucopyranoside + 1,4-benzoquinone 69% of the activity with D-glucose Agaricus bisporus methyl-beta-3-dehydro-D-glucopyranoside + hydroquinone - ? 373831 1.1.99.29 methyl-beta-D-glucopyranoside + 1,4-benzoquinone formation of the C-3 carbonyl derivative, 20% of the activity with D-glucose Leucoagaricus meleagris methyl-beta-3-dehydro-D-glucopyranoside + hydroquinone - ? 373831 1.1.99.29 methyl-beta-D-glucopyranoside + ferricenium ion 17% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 373832 1.1.99.29 additional information oxidative carbohydrate metabolism, pyranose 2-dehydrogenase may play an important role in fungal lignocellulose decomposition by interconnecting ligninolysis with degradation of cell wall polysaccharide components Agaricus bisporus ? - ? 89 1.1.99.29 additional information broad selectivity for sugar substrates, O2 does not act as oxidant, not: D-allose, D-altrose, D-arabinose, D-ribose, D-fructose, L-sorbose, lactose, D-arabinitol, dulcitol, D-mannitol Chlorophyllum rhacodes ? - ? 89 1.1.99.29 additional information enzyme is incapable of reducing O2 to H2O2, not: cytochrome c, NAD(P)+, nitroblue tetrazolium, low or no activity with D-altrose, D-fructose, D-lyxose, D-mannose, D-arabinitol, D-glucitol, D-mannitol or erythritol Agaricus bisporus ? - ? 89 1.1.99.29 additional information extremely broad substrate tolerance Leucoagaricus meleagris ? - ? 89 1.1.99.29 additional information with 1,4-benzoquinone as electron acceptor, PDH catalyzes the oxidation of numerous monosaccharides and oligosaccharides Agaricus bisporus ? - ? 89 1.1.99.29 additional information PDH can oxidise its substrate at the C-1, C-2 or C-3 as well as perform double oxidation at C-1,2, C-2,3 and it has no anomeric specificity. PDH does not show any detectable activity with oxygen Leucoagaricus meleagris ? - ? 89 1.1.99.29 additional information O2 is a poor electron acceptor Leucoagaricus meleagris ? - ? 89 1.1.99.29 additional information with 1,4-benzoquinone as electron acceptor, PDH catalyzes the oxidation of numerous monosaccharides and oligosaccharides Agaricus bisporus U3 ? - ? 89 1.1.99.29 additional information extremely broad substrate tolerance Leucoagaricus meleagris CCBAS 907 ? - ? 89 1.1.99.29 palatinose + acceptor relative activity towards D-glucose (100%): 89% Leucoagaricus meleagris ? - ? 406319 1.1.99.29 pyranose + acceptor - Agaricus bisporus 2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor - ? 359219 1.1.99.29 pyranose + acceptor - Chlorophyllum rhacodes 2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor - ? 359219 1.1.99.29 pyranose + acceptor - Agaricus bisporus U3 2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor - ? 359219 1.1.99.29 pyranose + acceptor - Agaricus bisporus 306 2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor - ? 359219 1.1.99.29 pyranose + acceptor - Chlorophyllum rhacodes 2,3-didehydropyranose + reduced acceptor - ? 406521 1.1.99.29 pyranose + acceptor - Agaricus xanthodermus 2,3-didehydropyranose + reduced acceptor - ? 406521 1.1.99.29 pyranose + acceptor - Leucoagaricus meleagris 2,3-didehydropyranose + reduced acceptor - ? 406521 1.1.99.29 pyranose + acceptor - Agaricus bisporus 2,3-didehydropyranose + reduced acceptor - ? 406521 1.1.99.29 pyranose + acceptor - Chlorophyllum rhacodes 2-dehydropyranose + reduced acceptor - ? 406522 1.1.99.29 pyranose + acceptor - Agaricus xanthodermus 2-dehydropyranose + reduced acceptor - ? 406522 1.1.99.29 pyranose + acceptor - Leucoagaricus meleagris 2-dehydropyranose + reduced acceptor - ? 406522 1.1.99.29 pyranose + acceptor - Agaricus bisporus 2-dehydropyranose + reduced acceptor - ? 406522 1.1.99.29 pyranose + acceptor - Leucoagaricus meleagris 2-dehydropyranose + reduced acceptor 2-dehydropyranose or 1-dehydropyranose or 3-dehydropyranose or 2,3-didehydropyranose ? 406522 1.1.99.29 pyranose + acceptor - Chlorophyllum rhacodes 3-dehydropyranose + reduced acceptor - ? 406523 1.1.99.29 pyranose + acceptor - Agaricus xanthodermus 3-dehydropyranose + reduced acceptor - ? 406523 1.1.99.29 pyranose + acceptor - Leucoagaricus meleagris 3-dehydropyranose + reduced acceptor - ? 406523 1.1.99.29 pyranose + acceptor - Agaricus bisporus 3-dehydropyranose + reduced acceptor - ? 406523 1.1.99.29 pyranoside + acceptor - Agaricus xanthodermus 3,4-didehydropyranoside + reduced acceptor - ? 424980 1.1.99.29 pyranoside + acceptor - Leucoagaricus meleagris 3,4-didehydropyranoside + reduced acceptor - ? 424980 1.1.99.29 raffinose + ferrocenium ion - Agaricus bisporus ? - ? 439870 1.1.99.29 sucrose + 1,4-benzoquinone quinone-dependent PDH oxidizes sucrose exclusively at C-3 of its terminal glucopyranosyl moiety, 11% of the activity with D-glucose Leucoagaricus meleagris 3'-dehydrosucrose + hydroquinone oxidation of sucrose at C-3 of its terminal glucopyranosyl moiety ? 374671 1.1.99.29 sucrose + 1,4-benzoquinone 9% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 374672 1.1.99.29 sucrose + 1,4-benzoquinone 63% of the activity with D-glucose Agaricus bisporus ? - ? 374672 1.1.99.29 sucrose + acceptor - Leucoagaricus meleagris ? - ? 398359 1.1.99.29 sucrose + acceptor relative activity towards D-glucose (100%): 46% Leucoagaricus meleagris 3'-dehydrosucrose + reduced acceptor - ? 406717 1.1.99.29 sucrose + ferricenium ion 6% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 374673 1.1.99.29 trehalose + 1,4-benzoquinone 7% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 374758 1.1.99.29 trehalose + 1,4-benzoquinone 54% of the activity with D-glucose Agaricus bisporus ? - ? 374758 1.1.99.29 trehalose + ferricenium ion 8% of the activity with D-glucose Chlorophyllum rhacodes ? - ? 374759 1.1.99.29 xylobiose + acceptor - Leucoagaricus meleagris ? - ? 406891 1.1.99.29 xylobiose + ferricenium ion - Leucoagaricus meleagris ? + ferrocene - ? 425082 1.1.99.29 xylooligosaccharide + acceptor - Agaricus bisporus ? - ? 461392 1.1.99.29 xylooligosaccharide + acceptor activity of the PDH1 enzyme from Agaricus bisporus toward the tested xylooligosaccharides is higher than that measured for the PDH1 enzyme from Leucoagaricus meleagris. Activity values decrease with increasing length of the xylooligosaccharide and when using acidic rather than neutral substrates. The enzyme from Agaricus bisporus (AbPDH1) fully oxidizes all linear xylooligosaccharides, and 60-100% of all substituted xylooligosaccharides, after 24 h under the tested reaction conditions. Oxidation is restricted to the reducing and non-reducing xylopyranosyl residues Agaricus bisporus ? - ? 461392 1.1.99.29 D-xylobiose + ferricenium ion - Leucoagaricus meleagris ? - r 451173 1.1.99.29 maltotriose + ferricenium ion - Leucoagaricus meleagris ? - r 373772