1.14.14.45 (E)-indol-3-ylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 = S-[(E)-N-hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O (1), overall reaction - 1.14.14.45 (E)-indol-3-ylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = 1-(1H-indol-3-yl)-2-aci-nitroethane + [oxidized NADPH-hemoprotein reductase] + H2O (1a) - 1.14.14.45 (E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 = S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O (2), overall reaction - 1.14.14.45 (E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = 1-aci-nitro-2-phenylethane + [oxidized NADPH-hemoprotein reductase] + H2O (2a) - 1.14.14.45 1-(1H-indol-3-yl)-2-aci-nitroethane + glutathione = S-[(E)-N-hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + H2O (1b), spontaneous - 1.14.14.45 1-aci-nitro-2-phenylethane + glutathione = S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + H2O (2b), spontaneous -