1.14.14.41 (E)-2-methylbutanal oxime + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O (1) overall reaction - 1.14.14.41 (E)-2-methylbutanal oxime = (Z)-2-methylbutanal oxime (1a) - 1.14.14.41 (E)-2-methylpropanal oxime + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O (2) overall reaction - 1.14.14.41 (E)-2-methylpropanal oxime = (Z)-2-methylpropanal oxime (2a) - 1.14.14.41 (Z)-2-methylbutanal oxime = 2-methylbutanenitrile + H2O (1b) - 1.14.14.41 (Z)-2-methylpropanal oxime = 2-methylpropanenitrile + H2O (2b) - 1.14.14.41 2-methylbutanenitrile + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O (1c) - 1.14.14.41 2-methylpropanenitrile + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O catalytic reaction mechanism, detailed overview -