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Literature summary extracted from

  • Ullrich, R.; Poraj-Kobielska, M.; Scholze, S.; Halbout, C.; Sandvoss, M.; Pecyna, M.J.; Scheibner, K.; Hofrichter, M.
    Side chain removal from corticosteroids by unspecific peroxygenase (2018), J. Inorg. Biochem., 183, 84-93 .
    View publication on PubMed

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
1.11.2.1 Mg2+ contains Mg2+ Marasmius rotula

Molecular Weight [Da]

EC Number Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
1.11.2.1 58
-
 gel filtration Marasmius rotula
1.11.2.1 62
-
 gel filtration Marasmius wettsteinii

Organism

EC Number Organism UniProt Comment Textmining
1.11.2.1 Cyclocybe aegerita B9W4V6
-
-
1.11.2.1 Marasmius rotula A0A023H437
-
-
1.11.2.1 Marasmius wettsteinii
-
-
-
1.11.2.1 Marasmius wettsteinii DSM 106021
-
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.11.2.1
-
 Marasmius wettsteinii

Specific Activity [micromol/min/mg]

EC Number Specific Activity Minimum [µmol/min/mg] Specific Activity Maximum [µmol/min/mg] Comment Organism
1.11.2.1 26
-
 with veratryl alcohol as substrate, at pH 5.5 and 23°C Marasmius rotula
1.11.2.1 99.6
-
 with veratryl alcohol as substrate, at pH 7.0 and 23°C Cyclocybe aegerita

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.2.1 11-deoxycortisol + H2O2 Reichstein's substance S Marasmius rotula ? + H2O
-
 ?
1.11.2.1 11-deoxycortisol + H2O2 Reichstein's substance S Marasmius wettsteinii ? + H2O
-
 ?
1.11.2.1 11-deoxycortisol + H2O2 Reichstein's substance S Marasmius wettsteinii DSM 106021 ? + H2O
-
 ?
1.11.2.1 4-nitrobenzaldehyde + H2O2
-
 Cyclocybe aegerita 4-nitrobenzoic acid + H2O
-
 ?
1.11.2.1 4-nitrobenzaldehyde + H2O2
-
 Marasmius rotula 4-nitrobenzoic acid + H2O
-
 ?
1.11.2.1 4-nitrobenzaldehyde + H2O2
-
 Marasmius wettsteinii 4-nitrobenzoic acid + H2O
-
 ?
1.11.2.1 4-nitrobenzaldehyde + H2O2
-
 Marasmius wettsteinii DSM 106021 4-nitrobenzoic acid + H2O
-
 ?
1.11.2.1 cortisone + H2O2
-
 Marasmius rotula cortisone 21-gem-diol + cortisone 21-oic acid + adrenosterone + H2O
-
 ?
1.11.2.1 cortisone + H2O2
-
 Marasmius wettsteinii cortisone 21-gem-diol + cortisone 21-oic acid + adrenosterone + H2O
-
 ?
1.11.2.1 cortisone + H2O2
-
 Marasmius wettsteinii DSM 106021 cortisone 21-gem-diol + cortisone 21-oic acid + adrenosterone + H2O
-
 ?
1.11.2.1 cortisone 21-al + H2O2
-
 Marasmius rotula cortisone 21-oic acid + H2O
-
 ?
1.11.2.1 cortisone 21-al + H2O2
-
 Marasmius wettsteinii cortisone 21-oic acid + H2O
-
 ?
1.11.2.1 additional information the enzyme shows no activity with cortisone and negligible oxidation of prednisone and 11-deoxycortisol Cyclocybe aegerita ?
-
 ?
1.11.2.1 prednisone + H2O2
-
 Marasmius rotula ? + H2O
-
 ?
1.11.2.1 prednisone + H2O2
-
 Marasmius wettsteinii ? + H2O
-
 ?
1.11.2.1 prednisone + H2O2
-
 Marasmius wettsteinii DSM 106021 ? + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Marasmius rotula veratraldehyde + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Marasmius wettsteinii veratraldehyde + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Marasmius wettsteinii DSM 106021 veratraldehyde + H2O
-
 ?

Subunits

EC Number Subunits Comment Organism
1.11.2.1 homodimer 2 * 46000, SDS-PAGE Cyclocybe aegerita
1.11.2.1 homodimer 2 * 32000, SDS-PAGE Marasmius rotula
1.11.2.1 homodimer 2 * 32500, SDS-PAGE Marasmius wettsteinii

Synonyms

EC Number Synonyms Comment Organism
1.11.2.1 UPO
-
 Cyclocybe aegerita
1.11.2.1 UPO
-
 Marasmius rotula
1.11.2.1 UPO
-
 Marasmius wettsteinii

Turnover Number [1/s]

EC Number Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
1.11.2.1 0.102
-
 cortisone at pH 5.5 and 23°C Marasmius wettsteinii
1.11.2.1 0.107
-
 cortisone at pH 5.5 and 23°C Marasmius rotula

Cofactor

EC Number Cofactor Comment Organism Structure
1.11.2.1 heme
-
 Cyclocybe aegerita
1.11.2.1 heme
-
 Marasmius rotula
1.11.2.1 heme
-
 Marasmius wettsteinii