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Literature summary extracted from

  • Aranda, C.; Ullrich, R.; Kiebist, J.; Scheibner, K.; Del Rio, J.; Hofrichter, M.; Martinez, A.; Gutierrez, A.
    Selective synthesis of the resveratrol analogue 4,4'-dihydroxy-trans-stilbene and stilbenoids modification by fungal peroxygenases (2018), Catal. Sci. Technol., 8, 2394-2401.
No PubMed abstract available

Cloned(Commentary)

EC Number Cloned (Comment) Organism
1.11.2.1 expressed in Aspergillus oryzae Coprinopsis cinerea
1.11.2.1 expressed in Aspergillus oryzae Cyclocybe aegerita

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.11.2.1 0.0141
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Cyclocybe aegerita
1.11.2.1 0.0153
-
 trans-stilbene at pH 7.0 and 24°C Marasmius rotula
1.11.2.1 0.0189
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Coprinopsis cinerea
1.11.2.1 0.0208
-
 trans-stilbene at pH 7.0 and 24°C Cyclocybe aegerita
1.11.2.1 0.0305
-
 trans-stilbene at pH 7.0 and 24°C Coprinopsis cinerea
1.11.2.1 0.0464
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Marasmius rotula

Organism

EC Number Organism UniProt Comment Textmining
1.11.2.1 Chaetomium globosum
-
-
-
1.11.2.1 Coprinopsis cinerea
-
-
-
1.11.2.1 Cyclocybe aegerita B9W4V6
-
-
1.11.2.1 Marasmius rotula A0A023H437
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.11.2.1 Q-Sepharose column chromatography, SP Sepharose column chromatography, and Mono-S ion-exchange column chromatography Cyclocybe aegerita
1.11.2.1 S-Sepharose column chromatography and SP-Sepharose column chromatography Coprinopsis cinerea

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.2.1 4-hydroxy-trans-stilbene + H2O2
-
 Chaetomium globosum 4,4'-dihydroxy-trans-stilbene + H2O
-
 ?
1.11.2.1 4-hydroxy-trans-stilbene + H2O2
-
 Cyclocybe aegerita 4,4'-dihydroxy-trans-stilbene + H2O
-
 ?
1.11.2.1 4-hydroxy-trans-stilbene + H2O2
-
 Coprinopsis cinerea 4,4'-dihydroxy-trans-stilbene + H2O
-
 ?
1.11.2.1 4-hydroxy-trans-stilbene + H2O2
-
 Marasmius rotula 4,4'-dihydroxy-trans-stilbene + H2O
-
 ?
1.11.2.1 additional information no activity with pinosylvin and resveratrol Chaetomium globosum ?
-
 ?
1.11.2.1 pinosylvin + H2O2
-
 Coprinopsis cinerea oxyresveratrol + oxypinosylvin + resveratrol + H2O
-
 ?
1.11.2.1 pinosylvin + H2O2
-
 Cyclocybe aegerita oxyresveratrol + resveratrol + H2O
-
 ?
1.11.2.1 resveratrol + H2O2
-
 Cyclocybe aegerita oxyresveratrol + H2O
-
 ?
1.11.2.1 resveratrol + H2O2
-
 Coprinopsis cinerea oxyresveratrol + H2O
-
 ?
1.11.2.1 trans-stilbene + H2O2
-
 Cyclocybe aegerita 4,4'-dihydroxy-trans-stilbene + tri-hydroxylated trans-stilbene + H2O
-
 ?
1.11.2.1 trans-stilbene + H2O2
-
 Coprinopsis cinerea 4,4'-dihydroxy-trans-stilbene + tri-hydroxylated trans-stilbene + H2O
-
 ?
1.11.2.1 trans-stilbene + H2O2
-
 Marasmius rotula 4,4'-dihydroxy-trans-stilbene + tri-hydroxylated trans-stilbene + H2O
-
 ?
1.11.2.1 trans-stilbene + H2O2
-
 Chaetomium globosum trans-stilbene epoxide + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Chaetomium globosum veratraldehyde + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Cyclocybe aegerita veratraldehyde + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Coprinopsis cinerea veratraldehyde + H2O
-
 ?
1.11.2.1 veratryl alcohol + H2O2
-
 Marasmius rotula veratraldehyde + H2O
-
 ?

Subunits

EC Number Subunits Comment Organism
1.11.2.1 ? x * 46000, SDS-PAGE Cyclocybe aegerita
1.11.2.1 ? x * 44000, SDS-PAGE Coprinopsis cinerea
1.11.2.1 ? x * 32000, SDS-PAGE Marasmius rotula

Synonyms

EC Number Synonyms Comment Organism
1.11.2.1 UPO
-
 Chaetomium globosum
1.11.2.1 UPO
-
 Cyclocybe aegerita
1.11.2.1 UPO
-
 Coprinopsis cinerea
1.11.2.1 UPO
-
 Marasmius rotula

Turnover Number [1/s]

EC Number Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
1.11.2.1 4.2
-
 trans-stilbene at pH 7.0 and 24°C Marasmius rotula
1.11.2.1 6.6
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Coprinopsis cinerea
1.11.2.1 9.1
-
 trans-stilbene at pH 7.0 and 24°C Coprinopsis cinerea
1.11.2.1 11.7
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Marasmius rotula
1.11.2.1 85.7
-
 trans-stilbene at pH 7.0 and 24°C Cyclocybe aegerita
1.11.2.1 225
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Cyclocybe aegerita

pI Value

EC Number Organism Comment pI Value Maximum pI Value
1.11.2.1 Marasmius rotula isoelectric focusing 5.3 5

kcat/KM [mM/s]

EC Number kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
1.11.2.1 250
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Marasmius rotula
1.11.2.1 270
-
 trans-stilbene at pH 7.0 and 24°C Marasmius rotula
1.11.2.1 300
-
 trans-stilbene at pH 7.0 and 24°C Coprinopsis cinerea
1.11.2.1 350
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Coprinopsis cinerea
1.11.2.1 4100
-
 trans-stilbene at pH 7.0 and 24°C Cyclocybe aegerita
1.11.2.1 16000
-
 4-hydroxy-trans-stilbene at pH 7.0 and 24°C Cyclocybe aegerita