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Literature summary extracted from

  • Stack, T.M.M.; Li, W.; Johnson, W.H.; Zhang, Y.J.; Whitman, C.P.
    Inactivation of 4-oxalocrotonate tautomerase by 5-halo-2-hydroxy-2,4-pentadienoates (2018), Biochemistry, 57, 1012-1021 .
    View publication on PubMed

Inhibitors

EC Number Inhibitors Comment Organism Structure
5.3.2.6 (2E,4Z)-2-bromo-5-hydroxyhexa-2,4-dienedioic acid
-
 Leptothrix cholodnii
5.3.2.6 (2E,4Z)-2-bromo-5-hydroxyhexa-2,4-dienedioic acid
-
 Pseudomonas putida
5.3.2.6 (2E,4Z)-2-chloro-5-hydroxyhexa-2,4-dienedioic acid
-
 Leptothrix cholodnii
5.3.2.6 (2E,4Z)-2-chloro-5-hydroxyhexa-2,4-dienedioic acid
-
 Pseudomonas putida
5.3.2.6 (2E,4Z)-2-fluoro-5-hydroxyhexa-2,4-dienedioic acid
-
 Leptothrix cholodnii
5.3.2.6 (2E,4Z)-2-fluoro-5-hydroxyhexa-2,4-dienedioic acid
-
 Pseudomonas putida
5.3.2.6 (2Z,4E)-5-bromo-2-hydroxypenta-2,4-dienoic acid
-
 Leptothrix cholodnii
5.3.2.6 (2Z,4E)-5-bromo-2-hydroxypenta-2,4-dienoic acid
-
 Pseudomonas putida
5.3.2.6 (2Z,4E)-5-chloro-2-hydroxypenta-2,4-dienoic acid
-
 Leptothrix cholodnii
5.3.2.6 (2Z,4E)-5-chloro-2-hydroxypenta-2,4-dienoic acid
-
 Pseudomonas putida
5.3.2.6 (2Z,4E)-5-fluoro-2-hydroxypenta-2,4-dienoic acid
-
 Leptothrix cholodnii
5.3.2.6 (2Z,4E)-5-fluoro-2-hydroxypenta-2,4-dienoic acid
-
 Pseudomonas putida
5.3.2.6 (3Z)-5-bromo-2-oxopent-3-enoic acid
-
 Leptothrix cholodnii
5.3.2.6 (3Z)-5-bromo-2-oxopent-3-enoic acid
-
 Pseudomonas putida
5.3.2.6 (3Z)-5-chloro-2-oxopent-3-enoic acid
-
 Leptothrix cholodnii
5.3.2.6 (3Z)-5-chloro-2-oxopent-3-enoic acid
-
 Pseudomonas putida
5.3.2.6 (3Z)-5-fluoro-2-oxopent-3-enoic acid
-
 Leptothrix cholodnii
5.3.2.6 (3Z)-5-fluoro-2-oxopent-3-enoic acid
-
 Pseudomonas putida

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate Leptothrix cholodnii
-
 (3E)-2-oxohex-3-enedioate
-
 r
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate Pseudomonas putida
-
 (3E)-2-oxohex-3-enedioate
-
 r
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate Leptothrix cholodnii SP-6
-
 (3E)-2-oxohex-3-enedioate
-
 r

Organism

EC Number Organism UniProt Comment Textmining
5.3.2.6 Leptothrix cholodnii
-
-
-
5.3.2.6 Leptothrix cholodnii SP-6
-
-
-
5.3.2.6 Pseudomonas putida Q01468
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
5.3.2.6
-
 Leptothrix cholodnii
5.3.2.6
-
 Pseudomonas putida

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
 Leptothrix cholodnii (3E)-2-oxohex-3-enedioate
-
 r
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
 Pseudomonas putida (3E)-2-oxohex-3-enedioate
-
 r
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
 Leptothrix cholodnii SP-6 (3E)-2-oxohex-3-enedioate
-
 r

Subunits

EC Number Subunits Comment Organism
5.3.2.6 ? x * 6812, electrospray ionization mass spectrometry Pseudomonas putida

Synonyms

EC Number Synonyms Comment Organism
5.3.2.6 4-OT
-
 Leptothrix cholodnii
5.3.2.6 4-OT
-
 Pseudomonas putida
5.3.2.6 4-oxalocrotonate tautomerase
-
 Leptothrix cholodnii
5.3.2.6 4-oxalocrotonate tautomerase
-
 Pseudomonas putida