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Literature summary extracted from

  • Yonemura, Y.; Ohyama, T.; Hoshino, T.
    Chemo-enzymatic syntheses of drimane-type sesquiterpenes and the fundamental core of hongoquercin meroterpenoid by recombinant squalene-hopene cyclase (2012), Org. Biomol. Chem., 10, 440-446.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
5.4.99.17 Alicyclobacillus acidocaldarius
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
5.4.99.17 (6E,10E)-2,6,10-trimethyldodeca-2,6,10-triene via bicyclic C8-cation Alicyclobacillus acidocaldarius (4aR,5S,8aS)-1,1,4a,5,6-pentamethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalene + (4aR,5S,8aS)-1,1,4a,5-tetramethyl-6-methylidenedecahydronaphthalene + (1R,2R,4aS,8aS)-1,2,5,5,8a-pentamethyldecahydronaphthalen-2-ol + (1R,2S,4aS,8aS)-1,2,5,5,8a-pentamethyldecahydronaphthalen-2-ol + (4aS,8aS)-4,4,7,8,8a-pentamethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalene + (3S,4aS,8aS)-3,4,4,8,8a-pentamethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalene
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 ?
5.4.99.17 2-((2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienyl)phenol + H2O
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 Alicyclobacillus acidocaldarius (3S,4aR,6aR,12aR,12bS)-4,4,6a,12b-tetramethyl-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-2H-benzo[a]xanthen-3-ol + 2 H+
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 ?
5.4.99.17 2-((2E,6E)-9-(3,3-dimethyloxiran-2-yl)-3,7-dimethylnona-2,6-dienyl)phenol
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 Alicyclobacillus acidocaldarius (4aS,6aR,12aR,12bS)-4,4,6a,12b-tetramethyl-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-2H-benzo[a]xanthene + 2-[[(1S,4aS,8aS)-2,5,5,8a-tetramethyl-1,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]methyl]phenol + 2-[[(1S,4aS,8aS)-5,5,8a-trimethyl-2-methylidenedecahydronaphthalen-1-yl]methyl]phenol
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 ?
5.4.99.17 BE-40644
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 Alicyclobacillus acidocaldarius ?
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 ?
5.4.99.17 farnesol
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 Alicyclobacillus acidocaldarius drimenol + albicanol + driman-8,11-diol + [(1S,2R,8aS)-2,5,5,8a-tetramethyl-2-[[(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl]oxy]decahydronaphthalen-1-yl]methanol drimane-type sequiterpenes ?
5.4.99.17 hongoquercin A
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 Alicyclobacillus acidocaldarius ?
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 ?
5.4.99.17 hongoquercin B
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 Alicyclobacillus acidocaldarius ?
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 ?
5.4.99.17 additional information enzyme substrate specificity in polycyclization reactions, overview Alicyclobacillus acidocaldarius ?
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 ?
5.4.99.17 squalene
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 Alicyclobacillus acidocaldarius hop-22(29)-ene the enzyme from Alicyclobacillus acidocaldarius yields pentacyclic hopene and hopanol (diplopterol) via a hopanyl cation from squalene ?

Synonyms

EC Number Synonyms Comment Organism
5.4.99.17 SHC
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 Alicyclobacillus acidocaldarius