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Literature summary extracted from

  • Aranda, E.; Kinne, M.; Kluge, M.; Ullrich, R.; Hofrichter, M.
    Conversion of dibenzothiophene by the mushrooms Agrocybe aegerita and Coprinellus radians and their extracellular peroxygenases (2009), Appl. Microbiol. Biotechnol., 82, 1057-1066.
    View publication on PubMed

Localization

EC Number Localization Comment Organism GeneOntology No. Textmining
1.11.2.1 extracellular
-
 Coprinellus radians
-
-
1.11.2.1 extracellular
-
 Cyclocybe aegerita
-
-

Organism

EC Number Organism UniProt Comment Textmining
1.11.2.1 Coprinellus radians
-
-
-
1.11.2.1 Cyclocybe aegerita
-
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.11.2.1
-
 Coprinellus radians
1.11.2.1
-
 Cyclocybe aegerita

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.2.1 dibenzothiophene + H2O2 in vivo Coprinellus radians peroxygenase converts about 60% of dibenzothiophene into dibenzothiophene sulfoxide and dibenzothiophene sulfone as the sole metabolites. In vitro a total of seven oxygenation products are detected after dibenzothiophene conversion by the purified peroxygenase with dibenzothiophene sulfoxide as major product Coprinellus radians ?
-
 ?
1.11.2.1 dibenzothiophene + H2O2 in vivo Agrocybe aegerita peroxygenase oxidizes dibenzothiophene (0.11 mM) by 100% within 16 days into eight different metabolites. Among the latter are mainly S-oxidation products (dibenzothiophene sulfoxide, dibenzothiophene sulfone) and in lower amounts ring-hydroxylation compounds (e.g., 2-hydroxy-dibenzothiophene). In vitro a total of 19 oxygenation products are detected after dibenzothiophene conversion by the purified peroxygenase with ring hydroxylation favored over S-oxidation with 2-hydroxy-dibenzothiophene as major product Cyclocybe aegerita ?
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.11.2.1 extracellular peroxygenase
-
 Coprinellus radians
1.11.2.1 extracellular peroxygenase
-
 Cyclocybe aegerita

General Information

EC Number General Information Comment Organism
1.11.2.1 physiological function extracellular peroxygenase are involved in the oxidation of heterocycles under natural conditions Coprinellus radians
1.11.2.1 physiological function extracellular peroxygenase are involved in the oxidation of heterocycles under natural conditions Cyclocybe aegerita