BRENDA - Enzyme Database

Selective esterification of phthalic acids in two ionic liquids at high temperatures using a thermostable lipase of Bacillus thermocatenulatus: A comparative study

Martin, J.R.; Nus, M.; Gago, J.V.; Sanchez-Montero, J.M.; J. Mol. Catal. B 52-53, 162-167 (2008)
No PubMed abstract available

Data extracted from this reference:

Activating Compound
EC Number
Activating Compound
Commentary
Organism
Structure
3.1.1.3
2-butanol
2-butanol enhances lipase activity
Geobacillus thermocatenulatus
Organism
EC Number
Organism
Primary Accession No. (UniProt)
Commentary
Textmining
3.1.1.3
Geobacillus thermocatenulatus
-
-
-
Substrates and Products (Substrate)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
3.1.1.3
isophthalate + 2-butanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid mono(1-methylpropyl)ester + isophthalic acid di(1-methylpropyl)ester + H2O
the yield is 34% monoester and 46% diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
isophthalate + cyclohexanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monocyclohexyl ester + H2O
the yield is 7% monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
isophthalate + cyclopentanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monocyclopentyl ester + H2O
the yield is 5% monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
isophthalate + ethanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monoethyl ester + isophthalic acid diethyl ester + H2O
the yield is 74% monoester and no diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 38% monoester and 24% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively
-
-
?
3.1.1.3
isophthalate + n-butanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monobutyl ester + H2O
the yield is 14% for the monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
phthalate + ethanol
-
693692
Geobacillus thermocatenulatus
phthalic acid monoethyl ester + phthalic acid diethyl ester + H2O
the yield is 49% monoester and 30% diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 67% monoester and 33% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively
-
-
?
3.1.1.3
terephthalate + ethanol
-
693692
Geobacillus thermocatenulatus
terephthalic acid monoethyl ester + terephthalic acid diethyl ester + H2O
the yield is 44% monoester and no diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 39% monoester and 51% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively
-
-
?
Activating Compound (protein specific)
EC Number
Activating Compound
Commentary
Organism
Structure
3.1.1.3
2-butanol
2-butanol enhances lipase activity
Geobacillus thermocatenulatus
Substrates and Products (Substrate) (protein specific)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
3.1.1.3
isophthalate + 2-butanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid mono(1-methylpropyl)ester + isophthalic acid di(1-methylpropyl)ester + H2O
the yield is 34% monoester and 46% diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
isophthalate + cyclohexanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monocyclohexyl ester + H2O
the yield is 7% monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
isophthalate + cyclopentanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monocyclopentyl ester + H2O
the yield is 5% monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
isophthalate + ethanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monoethyl ester + isophthalic acid diethyl ester + H2O
the yield is 74% monoester and no diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 38% monoester and 24% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively
-
-
?
3.1.1.3
isophthalate + n-butanol
-
693692
Geobacillus thermocatenulatus
isophthalic acid monobutyl ester + H2O
the yield is 14% for the monoester, no formation of diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer
-
-
?
3.1.1.3
phthalate + ethanol
-
693692
Geobacillus thermocatenulatus
phthalic acid monoethyl ester + phthalic acid diethyl ester + H2O
the yield is 49% monoester and 30% diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 67% monoester and 33% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively
-
-
?
3.1.1.3
terephthalate + ethanol
-
693692
Geobacillus thermocatenulatus
terephthalic acid monoethyl ester + terephthalic acid diethyl ester + H2O
the yield is 44% monoester and no diester in 1-butyl-3-methyl imidazolium tetrafluoroborate buffer and 39% monoester and 51% diester in 1-butyl-3-methyl imidazolium hexafluorophosphate buffer respectively
-
-
?