Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary extracted from

  • Xiong, Q.; Rocco, F.; Wilson, W.K.; Xu, R.; Ceruti, M.; Matsuda, S.P.
    Structure and reactivity of the dammarenyl cation: configurational transmission in triterpene synthesis (2005), J. Org. Chem., 70, 5362-5375.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
5.4.99.41 Arabidopsis thaliana
-
-
-

Reaction

EC Number Reaction Comment Organism Reaction ID
5.4.99.41 (3S)-2,3-epoxy-2,3-dihydrosqualene = lupeol the C17 configuration of the tetracyclic intermediate dammarenyl cation can be deduced from the angular methyl configuration of the pentacyclic or 6-6-6-6 tetracyclic product Arabidopsis thaliana

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
5.4.99.41 (18E)-22,23-dihydro-20-oxa-oxidosqualene the 20-oxa substitution has negligible effect on substrate binding and on the activation energies Arabidopsis thaliana 3beta-hydroxy-22,23,24,25,26,27-hexanor-17beta-dammaran-20-one + ? sole product ?
5.4.99.41 2,3-oxidosqualene
-
Arabidopsis thaliana lupeol
-
?