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Literature summary extracted from

  • Dominguez de Maria, P.; Pohl, M.; Gocke, D.; Groeger, H.; Trauthwein, H.; Stillger, T.; Walter, L.; Mueller, M.
    Asymmetric synthesis of aliphatic 2-hydroxy ketones by enzymatic carboligation of aldehydes (2007), Eur. J. Org. Chem., 2007, 2940-2944.
No PubMed abstract available

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
4.1.1.7 Mg2+ dependent Pseudomonas putida
4.1.2.38 Mg2+
-
 Pseudomonas fluorescens

Organism

EC Number Organism UniProt Comment Textmining
4.1.1.7 Pseudomonas putida
-
-
-
4.1.2.38 Pseudomonas fluorescens
-
 strain biovar I
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.1.7 acetaldehyde
-
 Pseudomonas putida (R)-acetoin
-
 ?
4.1.1.7 benzoylformate
-
 Pseudomonas putida benzaldehyde + CO2
-
 ?
4.1.1.7 isovaleraldehyde
-
 Pseudomonas putida (R)-5-hydroxy-2,7-dimethyloctan-4-one
-
 ?
4.1.1.7 additional information isobutyraldehyde, pivalaldehyde, and tert-butylacetaldehyde are no substrates Pseudomonas putida ?
-
 ?
4.1.1.7 n-butanal
-
 Pseudomonas putida (R)-5-hydroxyoctan-4-one
-
 ?
4.1.1.7 n-pentanal
-
 Pseudomonas putida (R)-6-hydroxydecan-5-one
-
 ?
4.1.1.7 propanal
-
 Pseudomonas putida 4-hydroxyhexan-3-one
-
 ?
4.1.2.38 acetaldehyde
-
 Pseudomonas fluorescens (R)-acetoin
-
 ?
4.1.2.38 benzoin
-
 Pseudomonas fluorescens benzaldehyde + benzaldehyde
-
 ?
4.1.2.38 cyclohexylaldehyde + acetaldehyde
-
 Pseudomonas fluorescens 1-cyclohexyl 2-hydroxypropanone
-
 ?
4.1.2.38 isovaleraldehyde
-
 Pseudomonas fluorescens (R)-5-hydroxy-2,7-dimethyloctan-4-one
-
 ?
4.1.2.38 additional information isobutyraldehyde, pivalaldehyde, and tert-butylacetaldehyde are no substrates Pseudomonas fluorescens ?
-
 ?
4.1.2.38 n-butanal
-
 Pseudomonas fluorescens (R)-5-hydroxyoctan-4-one
-
 ?
4.1.2.38 n-pentanal
-
 Pseudomonas fluorescens (R)-6-hydroxydecan-5-one
-
 ?
4.1.2.38 propanal
-
 Pseudomonas fluorescens 4-hydroxyhexan-3-one
-
 ?

Synonyms

EC Number Synonyms Comment Organism
4.1.1.7 BFD catalyzes the asymmetric ligation of aliphatic aldehydes to afford enantiomerically enriched 2-hydroxy ketones Pseudomonas putida
4.1.2.38 BAL
-
 Pseudomonas fluorescens

Cofactor

EC Number Cofactor Comment Organism Structure
4.1.1.7 thiamine diphosphate dependent Pseudomonas putida
4.1.2.38 thiamine diphosphate dependent Pseudomonas fluorescens