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Literature summary extracted from

  • Hischer, T.; Gocke, D.; Fernandez, M.; Hoyos, P.; Alcantara, A.R.; Sinisterra, J.V.; Hartmeier, W.; Ansorge-Schumacher, M.B.
    Stereoselective synthesis of novel benzoins catalysed by benzaldehyde lyase in a gel-stabilised two-phase system (2005), Tetrahedron, 61, 7378-7383.
No PubMed abstract available

Application

EC Number Application Comment Organism
4.1.2.38 synthesis stereoselective synthesis of novel benzoins catalysed by benzaldehyde lyase in a gel-stabilised two-phase system. (R)-1,2-di(3-furanyl)-2-hydroxyethanone, (R)-2-hydroxy-1,2-di(3-thienyl) ethanone, (R)-1,2-di(4-ethoxyphenyl)-2-hydroxyethanone, (R)-1,2-di(3-ethoxyphenyl)-2-hydroxyethanone, (R)-2-hydroxy-1,2-di(3-tolyl)ethanone, and (R)-1,2-di(benzofuran-2-yl)-2-hydroxyethanone are prepared with yields up to 31.8% and enantiomeric excess of more than 99% Pseudomonas fluorescens

General Stability

EC Number General Stability Organism
4.1.2.38 recombinant enzyme entrapped in polyvinyl alcohol and suspended in hexane is stable in hexane for 1 week at 4°C and for more than 1 month at -20°C Pseudomonas fluorescens

Organism

EC Number Organism UniProt Comment Textmining
4.1.2.38 Pseudomonas fluorescens
-
 biovar I
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.2.38 3-ethoxybenzaldehyde
-
 Pseudomonas fluorescens (R)-1,2-di(3-ethoxyphenyl)-2-hydroxyethanone
-
 ?
4.1.2.38 3-methylbenzaldehyde
-
 Pseudomonas fluorescens (R)-2-hydroxy-1,2-di(3-tolyl)-ethanone
-
 ?
4.1.2.38 4-ethoxybenzaldehyde
-
 Pseudomonas fluorescens (R)-1,2-di(4-ethoxyphenyl)-2-hydroxyethanone
-
 ?
4.1.2.38 benzofuran-2-carbaldehyde
-
 Pseudomonas fluorescens (R)-1,2-di(benzo-furan-2-yl)-2-hydroxyethanone
-
 ?
4.1.2.38 furan-3-carbaldehyde
-
 Pseudomonas fluorescens (R)-1,2-di(3-furanyl)-2-hydroxyethanone
-
 ?
4.1.2.38 thiophene-3-carbaldehyde
-
 Pseudomonas fluorescens (R)-2-hydroxy-1,2-di(3-thienyl)ethanone
-
 ?

Synonyms

EC Number Synonyms Comment Organism
4.1.2.38 BAL
-
 Pseudomonas fluorescens