Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary extracted from

  • Hirohara, H.; Nishizawa, M.
    Biochemical synthesis of several chemical insecticide intermediates and mechanism of action of relevant enzymes (1998), Biosci. Biotechnol. Biochem., 62, 1-9.
    View publication on PubMed

Application

EC Number Application Comment Organism
3.1.1.3 synthesis production of (S)-acetic acid 2-methyl-4-oxo-3-prop-2-ynyl-cyclopent-2-enyl ester, which is used as an intermediate in the synthesis of pyrethroids, which are used as insecticides. They show excellent insecticidal activities and a low toxicity in mammals. Arthrobacter sp.

Organism

EC Number Organism UniProt Comment Textmining
3.1.1.3 Arthrobacter sp.
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3.1.1.3 (S,R)-acetic acid 2-methyl-4-oxo-3-prop-2-ynyl-cyclopent-2-enyl ester + H2O
-
Arthrobacter sp. (R)-4-hydroxy-3-methyl-2-prop-2-ynyl-cyclopent-2-enone + (S)-acetic acid 2-methyl-4-oxo-3-prop-2-ynyl-cyclopent-2-enyl ester + acetate
-
?

Temperature Optimum [°C]

EC Number Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
3.1.1.3 40
-
-
Arthrobacter sp.

pH Optimum

EC Number pH Optimum Minimum pH Optimum Maximum Comment Organism
3.1.1.3 7
-
-
Arthrobacter sp.