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Literature summary extracted from

  • Croteau, R.; Satterwhite, D.M.; Wheeler, C.J.; Felton, N.M.
    Biosynthesis of monoterpenes. Stereochemistry of the enzymatic cyclization of geranyl pyrophosphate to (-)-endo-fenchol (1988), J. Biol. Chem., 263, 15449-15453.
    View publication on PubMed

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
4.2.3.10 Mn2+ Mn2+-dependent Anethum foeniculum

Organism

EC Number Organism UniProt Comment Textmining
4.2.3.10 Anethum foeniculum
-
 M. var. vulgare
-

Purification (Commentary)

EC Number Purification (Comment) Organism
4.2.3.10 partial Anethum foeniculum

Reaction

EC Number Reaction Comment Organism Reaction ID
4.2.3.10 geranyl diphosphate + H2O = (-)-endo-fenchol + diphosphate reaction mechanism Anethum foeniculum
a
4.2.3.10 geranyl diphosphate + H2O = (-)-endo-fenchol + diphosphate (3R)-linalyl diphosphate is an intermediate in the reaction Anethum foeniculum
a

Source Tissue

EC Number Source Tissue Comment Organism Textmining
4.2.3.10 fruit schizocarps Anethum foeniculum
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.2.3.10 geranyl diphosphate mechanism of the isomerization-cyclization reaction Anethum foeniculum (-)-endo-fenchol + diphosphate
-
 ?
4.2.3.10 geranyl diphosphate stereochemistry, syn-isomerization of substrate to (3R)-linalyl diphosphate and cyclization of the latter via the anti-endo-conformer Anethum foeniculum (-)-endo-fenchol + diphosphate
-
 ?
4.2.3.10 geranyl diphosphate (3R)-linalyl diphosphate is an intermediate in the reaction Anethum foeniculum (-)-endo-fenchol + diphosphate
-
 ?

Temperature Optimum [°C]

EC Number Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
4.2.3.10 30
-
 assay at Anethum foeniculum